The variety of kinetics expressions encountered in the literature and the unreasonably broad range of values reported for the kinetics constants of Acidithiobacillus ferrooxidans underscore the need for a unifying experimental procedure and for the development of a reliable kinetics equation. Following an extensive and critical review of reported experimental techniques, a method based on batch...

in the present study, the mechanical behavior of aa5052 aluminum alloy during cold deformation and subsequent isothermal annealing in a temperature range of 225-300oc was investigated using the uniaxial tensile test data. it is found that by increasing the annealing time and temperature the material yield strength is decreased. the microstructural investigations of the annealed samples show tha...

After considering the kinetical interaction principle (KIP) introduced in ref. Physica A 296, 405 (2001), we study in the Boltzmann picture, the evolution equation and the H-theorem for non extensive systems. The q-kinetics and the κ-kinetics are studied in detail starting from the most general non linear Boltzmann equation compatible with the KIP.

We study the master equation with time-dependent coefficients, a linear kinetic equation for the Markov chains or for the monomolecular chemical kinetics. For the solution of this equation a path summation formula is proved. This formula represents the solution as a sum of solutions for simple kinetic schemes (kinetic paths), which are available in explicit analytical form. The relaxation rate ...

An empirical rate equation was obtained for the methanation kinetics catalyzed by MCR-2X, a commercial catalyst prepared by Haldor-Topsoe. The studies were carried out in a fixed-bed reactor under differential conditions, and in a gradientless recycle reactor (Berry) over a range of total pressures, reactant concentractions (H2/CO ratios), and temperatures. The kinetics of methanation were foun...

Recent fluorescence spectroscopy measurements of single-enzyme kinetics have shown that enzymatic turnovers form a renewal stochastic process in which the inverse of the mean waiting time between turnovers follows the Michaelis-Menten equation. We study enzyme kinetics at physiologically relevant mesoscopic concentrations using a master equation. From the exact solution of the master equation w...

abstractbackground and objectives:the phosphorus is second limiting nutrient in soil for crop production after nitrogen. mobility and availability of phosphorus (p) in soils is affected by phosphorus desorption characteristics. information about the effect of organic matter on kinetics and thermodynamics of p desorption in calcareous soils of east azerbaijan province is limited. the objective o...

this study was done with the aim of investigating the kinetics of available phosphorus changes in treated soils with municipal solid waste compost, fertilizer and the mixture of these in two levels of first and second percent in eight calcareous soil samples and in a period of zero to 3600 hours in incubation conditions (fc moisture and 250c). the results showed that with time increasing, extra...