Commercial interest in perchlorates began in the late 1890s/early 1900s in Europe and the United States as a direct result of the pioneering efforts in rockets and their propulsion systems (Mendiratta et al. 1996). The production of ammonium perchlorate, the largest component of solid rocket propellants, far outpaced that of the other perchlorates listed in Table 4-1. Their commercial manufactu...

a series of amino derivative of 1-indene and 9-fluorene have been synthesized from their corresponding iminium salt, generated in situ in the concentrated ethereal lithium perchlorate solution, and 1-indenyl or 9-fluorenyl anions. the yields of the reactions depend on the kind of anion. addition of 1-indeny anion to the iminium salt gives the amino derivative of 1-indene, while addition of fluo...

A series of amino derivative of 1-indene and 9-fluorene have been synthesized from their corresponding iminium salt, generated in situ in the concentrated ethereal lithium perchlorate solution, and 1-indenyl or 9-fluorenyl anions. The yields of the reactions depend on the kind of anion. Addition of 1-indeny anion to the iminium salt gives the amino derivative of 1-indene, while addition of fluo...

In the title compound, [Li(C(8)H(16)O(4))(CD(3)CN)]ClO(4), the Li atom is penta-coordinate. The O atoms of the 12-crown-4 ether form the basal plane, whereas the N atom of the trideutero-aceto-nitrile occupies the apical position. The Li(+) atom is displaced by 0.794 (6) Å toward the apical position from the plane formed by the O atoms because the Li(+) atom is too large to fit in the cavity of...

A. Organic Analyses 218 1. General Organic Analyses 218 2. Pesticides 219 3. PAHs and PCBs 221 4. Dioxin 222 5. VOCs 223 6. Textile Dyes 223 7. Surfactants 223 8. Disinfection Byproducts 224 9. Taste and Odor Compounds 226 10. Algal and Bacterial Toxins 226 11. Other Organic Pollutants 227 B. Inorganic Analyses 229 1. Disinfection Byproducts 229 2. Perchlorate and Dissolved Gases 230 3. Multipl...

An experimental study was conducted on electrically controlled solid propellants to gain an understanding the effect of applied DC voltage combustion characteristics. A group polymer electrolytes comprising polyethylene oxide, lithium perchlorate, and ammonium perchlorate were created their behavior characterized. The electrolyte found decompose ignite readily with application a potential. deco...