the present work was carried out to evaluate the removal of p-nitrophenol by adsorption onto olive cake based activated carbon having a bet surface area of 672 m²/g. the batch adsorption experimental results indicated that the equilibrium time for nitrophenol adsorption by olive cake-based activated carbon was 120min. the adsorption data was modeled by equilibrium and kinetic models. the pseudo...

this research evaluates the efficiency of nanosized zno in the catalytic ozonation of 4-chloro-2-nitrophenol and determines the effect of ph on heterogeneous catalytic ozonation. the combined use of ozone and zno catalyst leads to conversion of 98% 4-chloro-2-nitrophenol during 5 min. in addition, it was found that in zno catalytic ozonation, the degradation efficiency of 4-chloro-2-nitrophenol...

Pseudomonas putida DLL-E4 can efficiently degrade para-nitrophenol and its intermediate metabolite hydroquinone. The regulation of para-nitrophenol degradation was studied, and PNP induced a global change in the transcriptome of P. putida DLL-E4. When grown on PNP, the wild-type strain exhibited significant downregulation of 2912 genes and upregulation of 845 genes, whereas 2927 genes were down...

A novel, magnetically separable composite photocatalyst, titania coated with magnetic activated carbon, is prepared by depositing TiO2 onto the surface of magnetic activated carbon which was prepared by directly adsorbing of magnetic Fe2O3 nanoparticles onto activated carbon. The samples are characterized by X-ray diffraction, scanning electron microscopy and vibration sample magnetometer. Spec...

This research evaluates the efficiency of nanosized ZnO in the catalytic ozonation of 4-chloro-2-nitrophenol and determines the effect of pH on heterogeneous catalytic ozonation. The combined use of ozone and ZnO catalyst leads to conversion of 98% 4-chloro-2-nitrophenol during 5 min. In addition, it was found that in ZnO catalytic ozonation, the degradation efficiency of 4-chloro-2-nitrophenol...

This work concerns a comparison of experimental and theoretical results of the electron charge density distribution and the electrostatic potential around the m-nitrophenol molecule (m-NPH) known for its interesting physical characteristics. The molecular experimental results have been obtained from a high-resolution X-ray diffraction study. Theoretical investigations were performed using the D...

Novel hollow mesoporous @M/CeO(2) (M = Au, Pd, and Au-Pd) nanospheres are created. The nanospheres can be used as effective nanoreactors with superior catalytic activity and stability for reduction of 4-nitrophenol due to their hollow mesoporous structural features.

A primary goal of protein engineering is to control catalytic activity. Here we show that through mutagenesis of three active site residues, the catalytic activity of a multicomponent monooxygenase is altered so that it hydroxylates all three positions of toluene as well as both positions of naphthalene. Hence, for the first time, an enzyme has been engineered so that its regiospecific oxidatio...

Objective: Although it was shown that p-nitrophenol is anti-androgenic in vivo, the molecular details of how p-nitrophenol inhibits AR signaling are still not quite clear. In this report, we want to figure out this signaling in human cells. Methods: (I) Cell viability assay; (II) endogenous expression of androgen-activated genes; (III) expression, and purification of the FK1 domain of FKBP51; (...

The compound p-nitrophenol, which shows the anti-androgenic activity, can easily become anthropogenic pollutants and pose a threat to the environment and human health. Previous work indicates that the anti-androgenic mechanism of p-nitrophenol is complex and may involve several components in the AR signaling pathway, but the molecular details of how p-nitrophenol inhibits AR signaling are still...