The preparation and thorough characterization of a hybrid magnetic carrier system for the possible transport of activated platinum-based anticancer drugs, as demonstrated for cisplatin (cis-[Pt(NH3)2Cl2], CDDP), are described. The final functionalized mag/Au-LA-CDDP* system consists of maghemite/gold nanoparticles (mag/Au) coated by lipoic acid (HLA; LA stands for deprotonated form of lipoic ac...

In this study, hydrogen production from starch wastewater using anaerobic sludge immobilized on maghemite nanoparticles (γ-Fe2O3) was investigated. Two anaerobic baffled reactors (ABR-1 and ABR-2) were operated at organic loading rate (OLR) of 3.63±0.43 g-COD/L.d and hydraulic retention time (HRT) of 10 h. The ABR-1 was inoculated with 3.5 g-VSS/L preheated sludge at 90°C for 30 minutes. The se...

We describe the synthesis of hybrid magnetic ellipsoidal nanoparticles that consist of a mixture of two different iron oxide phases, hematite (α-Fe2O3) and maghemite (γ-Fe2O3), and characterize their magnetic field-driven self-assembly. We demonstrate that the relative amount of the two phases can be adjusted in a continuous way by varying the reaction time during the synthesis, leading to stro...

BACKGROUND Magnetic fluids containing superparamagnetic iron oxide nanoparticles represent an attractive platform as nanocarriers in chemotherapy. Recently, we developed a formulation of maghemite nanoparticles coated with rhodium (II) citrate, which resulted in in vitro cytotoxicity enhanced up to 4.6 times when compared to free rhodium (II) citrate formulation on breast carcinoma cells. In th...

Iron fatty acid complexes (IFACs) are prepared via the dissolution of porous hematite powder in hot unsaturated fatty acid. The IFACs are then decomposed in five different organic solvents under reflux conditions in the presence of the respective fatty acid. The XRD analysis results indicate that the resulting NPs comprise a mixture of wustite, magnetite, and maghemite phases. The solvents with...

Maghemite particles were synthesized by using a combined combustion method and sonochemical step. was used as carrier to prepare supported Pt Pd catalysts after deposition via The immediately ready be (metals catalytically active) for the 2,4-dinitrotoluene hydrogenation produce 2,4-toluenediamine. most active Pd/maghemite bimetallic Pd-Pt/maghemite. easily separable reaction due their magnetic...

Maghemite (γ-Fe2O3) nanoparticles have been synthesized using a chemical coprecipitation method at different nitric acid concentrations as an oxidizing agent. Characterization of all samples performed by several techniques including X-ray diffraction (XRD), transmission electron microscopy (TEM), alternating gradient magnetometry (AGM), thermogravimetric analysis (TGA), dynamic light scattering...

in this study, iron oxide nanoparticles (maghemite) were used to remove ni (ii) and cr (vi) from mine’s waste water. first, by using novel single step, maghemite nanoparticles (?-fe2o3) produced at room temperature, without the use of natural solvents and oxides. the average particle size of the maghemite was estimated to be 14 nm, by transition electron microscope (tem(. various factors influe...

Nano crystals of γ-Fe2O3 (maghemite) were synthesized by emulsion precipitation method using kerosene as oil phase, SPAN80 (sorbitane monooleate) as the surfactant and sodium hydroxide as the precipitating agent. The characterization of the samples by FTIR (Fourier transform infra-red) and XRD (X-ray diffraction) techniques confirmed the formation of γ-Fe2O3 (maghemite). Analysis by SEM (scanni...

To study the photodegradation of organic pollutants at the interface of minerals and water in natural environment, three series of alumina-coupled iron oxides (Al(2)O(3)-Fe(2)O(3)-300, Al(2)O(3)-Fe(2)O(3)-420, and Al(2)O(3)-Fe(2)O(3)-550) with different alumina fraction were prepared and characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) and Barret-Joyner-Halender (BJH), and...