zinc (ⅱ) tricarboxylate (zn-btc) with metal-organic framework (mof) has been synthesized for the first time under solvothermal conditions and has been tested as an adsorbent for methane and carbon dioxide at standard temperature and pressure. the adsorbent was characterized by means of x-ray diffraction(xrd), brunauer-emmet-teller (bet), fourier transform infrared (ft-ir) and scanning electron ...

this  article  provides  an  overview  on  preparation,  design,  crystal structure  and  properties  of  some  metal-organic  frameworks  of carboxylate coordination polymers mixed with pyridine-functionality linkers  prepared  in  our  laboratory.  the  article  covers  coordination polymers  in  two-  and  three-dimensional  supramolecular architectures. the reported coordination polymers ex...

Nano-structured copper oxides were successfully prepared through direct calcination of 1D ladderlike metal-organic framework [Cu2(btec)(2,2'-bipy)2]∞, (btec = 1,2,4,5-benzenetetracarboxylate and 2,2'-bipy = 2,2'-bipyridine) and porous coordination polymer [Cu(BDC)(bipy)](BDCH2), (BDC = 1,4-benzenedicarboxylate; bipy = 4,4'-bipyridine). The nano-structure of the as-synthesized samples are charac...

Metal-organic frameworks comprising metal-carboxylate cluster vertices and long, branched organic linkers are the most porous materials known, and therefore have attracted tremendous attention for many applications, including gas storage, separations, catalysis and drug delivery. To increase metal-organic framework porosity, the size and complexity of linkers has increased. Here we present a pr...