An efficient and mild methodology for rapid and efficient synthesis of isatin Schiff bases was described under microwave irradiation and solvent free condition.aromatic or heterocyclic Primary amines and isatin could be selectively reacted under microwave irradiation into the corresponding isatin Schiff bases in high yields and short reaction time.  

tripropylammonium fluorochromate(vi) (tpafc), is an efficient and new reagent, which isprepared easily and oxidizes thiols to the corresponding disulfides, quickly. the reactions areperformed cleanly and are controlled to stop at the disulfide stage, without over-oxidation andside products. coupling of thiols to their corresponding disulfides, are studied in solution atroom temperature and in s...

a new dimeric orthopalladated complex was synthesized via reaction of 2,3-dimethoxy benzaldehyde oxime with palladium chloride and lithium chloride in methanol as solvent and sodium acetate as base at room temperature. the catalytic activity of this dimeric [pd{c6h2(-ch=noh)-(ome)2-2,3}(µ-cl)]2 complex as an efficient, air, and moisture tolerant catalyst was investigated in mizoroki–heck cross ...

Hyssopus of­ficinalis L. is one of the most important medicinal plants. Medicinal herbs are contaminated by microorganisms. Conventional methods for reducing of microbial loads such as ethylene oxide, propylene oxide and also use of steam are hazardous and instead, non-thermal process such as microwave and gamma radiation are being used widely in order to eliminate the microbial contaminations ...

background & aim: a simple and rapid microwave- assisted extraction (mae) procedure was developed and optimized for the isolation of borneol and bornyl acetate from ferulago macrocarpa. ferulago macrocarpa (apiaceae) is an endemic plant in iran. experimental: dried powdered aerial parts of plants were soaked in water and irradiated with microwave in a clevenger extraction approach under opt...

microwave-assisted three component cyclocondensation reactions of aldehydes, amides and dienophiles in the presence of acetic anhydride and para-toluenesulfonic acid as a catalyst to afford the highly substituted cyclohexene derivatives, in relatively good yields after several minutes are reported.

this paper describes laboratory scale experiments examining the impact of microwave irradiation on the granular activated carbon (gac) exposed to toluene, a common organic vapor frequently released into work environment as well as outdoor. a stream containing 300 ppm toluene was supplied and passed through the granular activated carbon. the saturated adsorbent was placed in a quartz glass react...

Microwave irradiation during tissue fixation and immunostaining reduces the sample preparation time. Microwave irradiation also facilitates the penetration of fixatives and antibody solutions into the tissues, resulting in efficient fixation and reduction of non-specific antibody binding, respectively. Experimental procedures involving immunofluorescence microscopy are time-consuming as this me...

The work describes the accelerated enzymatic digestion of several proteins in various solvent systems under microwave irradiation. The tryptic fragments of the proteins were analyzed by matrix-assisted laser desorption/ionization mass spectrometry. Under the influence of rapid microwave heating, these enzymatic reactions can proceed in a solvent such as chloroform, which, under traditional dige...

background: there are many varieties of compounds in chemical and petrochemical wastewater. one of the important members of the chlorophenols (cps) family is ρ-chlorophenol. this pollutant is introduced into the environment through various human activities such as waste incineration, uncontrolled use of wood preservatives, pesticides, fungicides and herbicides, as well as via bleaching the pulp...