Experiments on miscible, buoyantly unstable reaction-diffusion fronts and non-reacting displacement fronts in Hele-Shaw cells show a fingering-type instability whose wavelengths (λ) are consistent with an interfacial tension (Σ) caused by the change in chemical composition, even though the solutions are miscible in all proportions. The relation Σ ≈ K/τ , where τ is the interface thickness and K...

The measurement of the minimum miscibility pressure (MMP) is one of the most important steps in the project design of miscible gas injection for which several experimental and modeling methods have been proposed. On the other hand, the standard procedure for compositional studies of miscible gas injection process is the regression of EOS to the conventional PVT tests. Moreover, this procedure d...

Enzymatic synthesis of oligopeptides from l-phenylalanine ethyl ester hydrochloride (l-Phe-Et.HCl) and other l-form hydrophobic amino acid ester hydrochlorides in water miscible organic cosolvents was studied. Different proteases, water miscible cosolvents, and effect of different ratios of water miscible cosolvents for protease-catalyzed oligo-phenylalanine [oligo(l-Phe)] were compared. The im...

Miscible gas injection, as an Enhanced Oil Recovery (EOR) method, can improve the recovery factor by swelling the residual oil and phasing out the interfacial tension [1]. However, the sweep efficiency of miscible gas injection is not satisfactory because of conformance problems, such as viscous fingering, channelling and gravity override [2]. Foam can solve the problems associated with gas inj...

The average glass transition temperatures, Tg, of thin homopolymer films exhibit a thickness dependence, Tg(h), associated with a confinement effect and with polymer-segment-interface interactions. The Tg's of completely miscible thin film blends of tetramethyl bisphenol-A polycarbonate (TMPC) and deuterated polystyrene (dPS), supported by SiO(x)/Si, decrease with decreasing h for PS weight fra...

A simple kinetic model of a two-component deformable and reactive bilayer is presented. The two differently shaped components are interconverted by a nonequilibrium reaction, and a phenomenological coupling between local composition and curvature is proposed. When the two components are not miscible, linear stability analysis predicts, and numerical simulations show, the formation of stationary...

We study the fingering instability of the interface between two miscible fluids, a colloidal suspension and its own solvent. The temporal evolution of the interface in a Hele-Shaw cell is found to be governed by the competition between the nonlinear viscosity of the suspension and an off-equilibrium, effective surface tension Γe. By studying suspensions in a wide range of volume fractions, ΦC, ...

The displacement of a more viscous fluid by a miscible, less viscous one of lower density in a horizontal capillary tube is studied by means of Stokes flow simulations. Both axisymmetric and three-dimensional simulations are conducted at Péclet numbers up to 104, in order to resolve discrepancies between earlier simulations by [C.Y. Chen, E. Meiburg, Miscible displacements in capillary tubes. P...

The effect of nanoparticles (NP) on chain dimensions in polymer melts has been the source of considerable theoretical and experimental controversy. We exploit our ability to ensure a spatially uniform dispersion of 13 nm silica NPs miscible in polystyrene melts, together with neutron scattering, x-ray scattering, and transmission electron microscopy, to show that there is no measurable change i...