Vanadium (III) gives a greenish- yellow complex with anthranilic acid in presence of pyridine. The complex is extractable with chloroform and is used for photometric determination of vanadium by measuring the absorbance at 390 nm against a reagent blank. Beer's Law holds good in the range of 1-20 pg V/ml. Moderate amounts of Pb (II) , Ca (II) , Sr (II) , Ba (II) , Cd (II) , Mg (II) , Mn (II...

Ionophore-based ion-exchange nanosphere emulsion was prepared and tested for the determination of thiocyanate. The emulsified nanosphere contained the cationic additive tridodecylmethyl ammonium chloride (TDMAC), the plasticizer, and the ionophore Mn(III)-salophen or Mn(III)-salen. This emulsion was used as titrating agent for thiocyanate complexation with ionophores, which could be transduced ...

In the title complex, [Mn(II)Mn(III) (2)(C(11)H(13)NO(4))(2)(CH(3)CO(2))(4)(H(2)O)(2)]·2CH(3)CN·2H(2)O, there are two Mn(III) and one Mn(II) atoms. The Mn(II) atom lies on an inversion center and the Mn(III)-Mn(II)-Mn(III) angle is therefore 180°, as required by crystallographic symmetry. The Mn(III) and Mn(II) atoms are six-coordinated in a distorted octa-hedral geometry. In the crystal, compl...

Herein we describe the chemical reactivity of the mononuclear [Mn(II)(N4py)(OTf)](OTf) (1) complex with hydrogen peroxide and superoxide. Treatment of 1 with one equivalent superoxide at -40 °C in MeCN formed the peroxomanganese(III) adduct, [Mn(III)(O2)(N4py)](+) (2) in ~30% yield. Complex 2 decayed over time and the formation of the bis(μ-oxo)dimanganese(III,IV) complex, [Mn(III)Mn(IV)(μ-O)2(...

In the present study a cloud-point extraction process using non-ionic surfactant Triton X-114 for selective extraction of gallium from aqueous solutions was developed. The method is based on the complex formation of Ga (III) with N, N′ -bis (salycilidene)-1, 2-phenylenediamine (salophen) as a chelating agent in buffer media of pH 5. After phase separation and dilution of the surfactant-rich pha...

In this study, Mn (III) salen complex was synthesized and immobilized onto the graphene oxide, which is modified by 3-chloropropyltrimethoxy silane. Heterogeneous catalyst was characterized by X-ray diffraction, transmission electron microscopy, thermogravimetric analysis, fourier transform infrared spectra, nitrogen adsorption−desorption isotherm and atomic absorption spectroscopy. The catalyt...