In this work, we have modified a synthesized Y-type zeolite (Si/Al = 2.5), with three different amines to investigate of the influence of adsorbent’s surface modification on CO2 selectivity over CH4. The pristine and amine-functionalized NaY zeolites were characterized by X-ray diffraction (XRD), thermal gravimetric analysis (TGA), Fourier transform infrared (FT-IR), and N2 adsorption. The resu...

INTRODUCTION The research made in this PhD thesis fits the current trend in the development of new advanced composite electrode materials with high performance and parameters. The composite materials has new physical and chemical properties that are not present in its components taken individually. The new electrode materials were obtained by combination of conducting polymers, such as polypyrr...

Structural properties of a series of mordenite and ZSM-5 zeolites with different framework Al distribution modified with oxygenated extraframework Ga, Zn, Al, Cu and Fe complexes were investigated by means of periodic density functional theory calculations. It is demonstrated that mononuclear oxygenated and hydroxylated cationic metal complexes in high-silica zeolites tend to self-organize into...

The aim of this study was to investigate the removal of Escherichia coli and heavy metals (Pb, Cd 2+ and Zn ) from wastewater using silver-modified clinoptilolite under different experimental conditions through the combined disinfection of pathogenic microorganisms by the silver ions and sorption of heavy metals on clinoptilolite. Batch experiments were conducted to look at the effects of initi...

Zeolites are widely used in wastewater and contaminated water refinement due to their great adsorption properties. However, Clinoptilolite (as one type of Zeolites) has a relatively low adsorption capacity at least for arsenic ions. Therefore, in order to increase the adsorption capacity, natural Clinoptilolite was modified with sulfuric acid and various tests were then conducted to determine t...

We determined the ability of two iron-and-zeolite materials to remove arsenic from groundwater. The first material is composed of iron, surfactant-modified zeolite, and hard silicate foam, and is known as Surfactant-Modified Zeolite/ Zero-Valent Iron (SMZ/ZVI). The second material is a new formulation that consists of iron-modified zeolite (IMZ). We prepared eight different prototypes of IMZ fo...

We present synthesis, characterization and testing results of our applied research project, which focuses on the effects of surface and skeletal modification of zeolites for significant enhancements in current hydrocarbon (HC) separations. Zeolites are commonly used by the chemical and petroleum industries as catalysts and ion-exchangers. They have high potential for separations owing to their ...

This sixty-eighth volume of IARC Monographs considers certain forms of crystalIine and amorphous silica, some silicates (palygorskite, also called attapulgite; sepiolite; wollastonite; and some natura1 and synthetic zeolites, exc1uding erionite), coa1 dust and para-aramid fibrils. Some of these agents are fibrous in nature (palygorskite, sepiolite, wollastonite and sorne natural zeolites, as we...

Various metal-β zeolites have been synthesized under similar ion-exchange conditions. During the exchange process, the nature and acid strength of the used cations modified the composition and textural properties as well as the Brönsted and Lewis acidity of the final materials. Zeolites exchanged with divalent cations showed a clear decrease of their surface Brönsted acidity and an increase of ...

Adsorption of 1-propanethiol on Co and Cd modified, synthetic (3A, 4A and 13X) zeolites were studied by FTIR (Fourier Transform Infrared) spectroscopy and SEM-EDX (Scanning Electron Microscope-Energy Dispersive X-Ray) graphics. Amount of metal cations on mentioned zeolites was measured by AAS (Atomic Absorption Spectrometer). Based on divalent cations of zeolites, it was assumed that cations ma...