Mononuclear Pt(II) and the first dinuclear Pt(II) complexes along with a cyclometalated heterobimetallic Ir(III)/Pd(II) complex bearing mesoionic carbene donor ligands are presented starting from the same bis-triazolium salt. The mononuclear Pt(II) complex possesses a free triazole moiety which is generated from the corresponding triazolium salt through an N-demethylation reaction, whereas the ...

Extensive π-stacking interactions in a crystalline mononuclear Dy complex give rise to phase-sensitive color-tuneable emission and pure white light generation allow for intense NIR by photoexcitation over broad spectral range.

background: atherosclerosis, a chronic inflammatory disease of the vessel wall is characterized by local and systemic immune responses to a variety of antigens. oxidized low-density lipoprotein (oxldl) is considered as an important determining factor in the pathogenesis of atherosclerosis. objective: the purpose of this study was to investigate the degree of peripheral blood mononuclear cells (...

The development of molecule-based switchable multifunctional materials remains an important challenge in molecular science. In particular, achieving high proton conductivities spin crossover (SCO) compounds is significant interest as the state can be controlled via transfer induced by electric field, which leads to magnetoelectric effects and spintronics. However, best our knowledge, no studies...

Abstract Tuberous sclerosis complex (TSC) is a multisystem disorder caused by loss-of-function mutations in TSC1/2 proteins. This results constitutive mTOR activation and predisposes to the development of benign tumours, with renal angiomyolipomas (AMLs) tuber-related drug-resistant epilepsy (DRE) being major causes morbidity mortality adults. Despite central role leukocyte biology beneficial i...