A formamide molecule is allowed to form a CH O H-bond with a glycine dipeptide in both its C5 and C7 internal conformations. As this intermolecular H-bond is elongated, the contraction of the CAH covalent bond is monitored, as is its vibrational stretching frequency and intensity, along with NMR chemical shifts of the atoms involved in the H-bond. The degree of shortening of the CAH bond become...

Nuclear magnetic resonance (NMR) experiments on carbon-13 in the solid state were done with cross polarization (CP) and magic angle spinning (MAS) in order to overcome the low NMR sensitivity of (13)C and the chemical shift anisotropy, respectively. In the present research, CPMAS (13)C-NMR spectra were collected by modulating the contact time needed for cross polarization (variable contact time...

The cancellation of self-generated components of sensory inputs is a key function of sensory feedback pathways. In many systems, cerebellar parallel fiber feedback mediates this cancellation through anti-Hebbian plasticity, resulting in the generation of a negative image of the reafferent inputs. Parallel fiber feedback involves direct excitation and disynaptic inhibition as well as synaptic pl...

abstract: this paper presents the results of pullout tests on uniaxial geogrid embedded in silica sand under monotonic and cyclic pullout forces. the new testing device as a recently developed automated pullout test device for soil-geogrid strength and deformation behavior investigation is capable of applying load/displacement controlled monotonic/cyclic forces at different rates/frequencies an...

We consider a “length-biased” shift-dependent information measure, related to the differential entropy in which higher weight is assigned to large values of observed random variables. This allows us to introduce the notions of “weighted residual entropy” and “weighted past entropy”, that are suitable to describe dynamic information of random lifetimes, in analogy with the entropies of residual ...

Article history: Received 17 December 2014 Received in revised form 1 December 2015 Accepted 3 December 2015 Available online 19 December 2015 The data for the lightflux degradation and chromaticity shift of LED lamps exhibits a considerable amount of scatter due to intrinsic and extrinsic factors. In this study, some degradation models, such as the gamma process model, were reviewed in terms o...

In this paper, we first propose a maximum likelihood estimator (MLE) of a change point in highyield processes, where the only assumption is that the change belongs to a family of monotonic changes. Following a signal from the cumulative count of conforming (CCC) control chart, the performance of the proposed monotonic change-point estimator is next evaluated by comparing its performances to the...