Porous clay heterostructures (PCH) based on modified montmorillonite were synthesized using different reaction conditions (different hydration degrees, pH values and reaction times). The PCH precursors and PCH were characterized using FTIR Spectroscopy and X-Ray Diffractions (XRD). The XRD results showed that basal distance of porous clay heterostructures was significantly influenced by the mod...

The feasibility of constructing polymer/clay nanocomposites with polypeptides as the matrix material is shown. Cationic poly-L-lysine HBr (PLL) was reinforced by sodium montmorillonite clay. The PLL/clay nanocomposites were made via the solution-intercalation film-casting technique. X-ray diffraction and transmission electron microscopy data indicated that montmorillonite layers intercalated wi...

The important characteristics of polymer/clay nanocomposites are stability, barrier properties and in the case of polyvinyl chloride also plasticizer migration into other materials. Therefore, the permeation properties of polymer/clay nanocomposites are discussed in this paper. The attention was focused to the polyethylene (PE) and polyvinyl chloride (PVC). Natural type of montmorillonite MMTNa...

nano zno/ montmorillonite composite were prepared by sol gel method under ultrasonic irradiation from directly mixing montmorillonite nano clay into zinc gel. the zn(ch3coo)2.2h2o and montmorillonite nano clay was used as precursor. the zinc acetate was dissolved in di water and, nh3 (aq) solution was dropped into the zinc solution until ph 9 consequently the zinc gel was produced. the montmori...

Controlled-release herbicide formulations have been shown to decrease the leaching potential of several herbicides under laboratory and Ðeld conditions. The utility and efficacy of these formulations may be improved by combining several herbicides and a fertilizer source in a single formulation. The objective of these studies was to develop granular alginate formulations that were composed of a...

The sorption capacity of montmorillonite clay minerals for small cations, such as Ni , can be greatly enhanced by modifying the clay mineral with Al(III). In this study, the mechanisms of Ni uptake by Al-modified montmorillonite were studied using extended x-ray absorption fine structure (EXAFS) spectroscopy of powders and polarized EXAFS spectroscopy of self-supporting clay films to delineate ...

Polymer-layered silicate nanocomposites belong to a new class of hybrid materials consisting of organic-synthetic polymer matrix and inorganic filler-layered structure clay minerals. The paper presents the results of FTIR, NMR, and SAXS studies of poly(ε-caprolactone)/sodium montmorillonite nanocomposites. We observed a correlation between the concentration of poly(ε-caprolactone) in nanocompos...

Removal of Cr(VI) from aqueous solutions under different conditions was investigated using either clay (montmorillonite) or micelle-clay complex, the last obtained by adsorbing critical micelle concentration of octadecyltrimethylammonium ions onto montmorillonite. Batch experiments showed the effects of contact time, adsorbent dosage, and pH on the removal efficiency of Cr(VI) from aqueous solu...

The aim of this study was to understand the interactions between alkylammonium cations present as monomers and micelles and a clay mineral, montmorillonite, to develop slow release formulations of anionic herbicides, such as sulfometuron (SFM) whose leaching in soils is an environmental and economic problem. In the proposed formulation the herbicide is incorporated in positively charged micelle...

The thermal properties such as specific heat capacity and heat dissipation of peloids play an important role in therapeutic applications. Therefore, these properties were determined on the peloids samples taken from spas where peloid applications are used in Turkey. In addition, some pure clay minerals were investigated to determine their suitability as possible constituents of therapeutic pelo...