Based on a facile vapor-phase transport method without any catalyst and template, one-dimensional single-crystalline bismuth oxide (Bi2O3) micro/nanoribbons were fabricated on silicon substrates in large quantities and morphology-controlled fabrication of Bi2O3 was achieved from a single precursor. The widths of Bi2O3 ribbons varied from 0.2 to 20 microm depending on the deposition temperatures...

in the present work, zno/bi2o3, sno2/bi2o3/bi2o4 mixed oxide, bi2o3 rod-like and sno2 nanoparticle have been synthesized. the obtained samples were characterized by field emission scanning electron microscopy (fe-sem) and x-ray diffraction (xrd). the optical properties of samples were evaluated by uv-vis spectrophotometer. the photocatalytic activity of samples was evaluated by decolorization o...

Bismuth oxide (Bi2O3)-doped yttria-stabilized zirconia (YSZ) were prepared via the solid state reaction method. X-ray diffraction and electron diffraction spectroscopy results indicate that doping with 2 mol% Bi2O3 and adding 10 mol% yttria result in a stable zirconia cubic phase. Adding Bi2O3 as a dopant increases the density of zirconia to above 96%, while reducing its normal sintering temper...

This work is a culmination of several corresponding studies designed to probe the initiation and reaction of aluminum nanothermite systems. The main diagnostic tool used in this study is a Temperature-Jump/Time-of-Flight Mass Spectrometer (T-Jump/TOFMS), which uses a filament heating method capable of very high heating rates up to 106 oC/s, while spectra are simultaneously obtained at a time re...

New data are presented on the phase equilibria and crystal chemistry of the binary systems CaO-Bi2O3 and CaO-CuO and the ternary CaO-Bi2O3-CuO. Symmetry data and unit cell dimensions based on single crystal and powder x-ray diffraction measurements are reported for several of the binary CaO-Bi2O3 phases, including corrected compositions for Ca4Bi6O13 and Ca2Bi2O5. The ternary system contains no...

The cover picture shows the degradation of the model dye rhodamine B (RhB) in water using b-Bi2O3 nanoparticles as photocatalyst, which was prepared from preorganized bismuth oxido clusters. In the background, a homemade photoreactor for in situ studies is shown, including the decolorizing process of the aqueous RhB solution as observed during visible light irradiation. The catalytic cycle show...

COVER PICTURE Maik Schlesinger, Marcus Weber, Steffen Schulze, Michael Hietschold, and Michael Mehring* The cover picture shows the degradation of the model dye rhodamine B (RhB) in water using β-Bi2O3 nanoparticles as photocatalyst, which was prepared from preorganized bismuth oxido clusters. In the background, a homemade photoreactor for in situ studies is shown, including the decolorizing pr...

Photocatalytic studies under visible light irradiation using nanosized β-Bi2O3 are reported. β-Bi2O3 nanoparticles are prepared starting from the well-defined bismuth oxido cluster [Bi38O45(OMc)24(DMSO)9]⋅2 DMSO⋅7 H2O (OMc=O2CC3H5) using a straightforward hydrolysis and annealing protocol. Powder X-ray diffraction studies, transmission electron microscopy, diffuse reflectance UV/Vis spectroscop...

The potential of UV-light for the photochemical synthesis and stabilization of non-equilibrium crystalline phases in thin films is demonstrated for the β-Bi2O3 polymorph. The pure β-Bi2O3 phase is thermodynamically stable at high temperature (450-667 °C), which limits its applications in devices. Here, a tailored UV-absorbing bismuth(III)-N-methyldiethanolamine complex is selected as an ideal p...