There is increasing international interest in naphthenic acids (NAs, classical formula C(n)H(2n+Z)O(2)) found in the oil sands from Alberta, Canada and in petroleum from around the world. The complexity of NAs poses major analytical challenges for their quantification and characterization. We used ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectr...

Increasingly, crudes of high acidity are observed in production of petroleum reserves. Naphthenic acids, which are generally cyclic and branched aliphatic carboxylic acids, are interfacially active and adsorb at water–oil interfaces to form monolayers, liquid crystalline films, and other colloidal structures. A serious challenge in petroleum production is the resulting stabilization of water-in...

Water soluble organic compounds (OCs), including naphthenic acids (NAs), are potentially toxic constituents of oil sands process-affected water (OSPW) that is generated during extraction of bitumen from Alberta oil sands. Ozonation can decrease concentrations of OCs in OSPW. However, effects of ozonated-OSPW on multicellular organisms are unknown. A 10-day and a chronic exposure of Chironomus d...

This paper presents chemical composition and aquatic toxicity characteristics of a commercial sample of naphthenic acids (NAs). Naphthenic acids are derived from the refining of petroleum middle distillates and can contribute to refinery effluent toxicity. NAs are also present in oil sands process-affected water (OSPW), but differences in the NAs compositions from these sources precludes using ...

Naphthenic acids are the most significant environmental contaminants resulting from petroleum extraction from oil sands deposits. In this study, a mixture of naphthenic acids isolated from Athabasca oil sands (AOS) tailings pond water was used in acute and subchronic toxicity tests with rodents, in order to assess potential risks posed to terrestrial wildlife. Dosages were chosen to bracket wor...

Naphthenic acids and TAN are one of the ever-increasing crucial problems in oil, shale oil and sand oil industry and also environment protection. Furtherer, they increases the corrosion of some parts of a refinery and transport pipelines and also can create nanoemulsions and make complicated the refining process especially in desalters. To prevent these problems it is important to first obtain ...