toktam faal rastegar was born in quchan (iran). she completed her b.sc. in chemistry in 2005 from ferdowsi university, mashhad. she was graduated from m.sc. degree in organic chemistry from bu-ali sina university (2008), hamadan, iran. she is currently organic chemistry ph.d student under the supervision of prof. a. khazaei and prof. m.a. zolfigol in department of chemistry at bu-ali sina unive...

3-(2-furanyl)-2-propenoic acid has been used to prepare a new series of organotin complexes of general formula r3snl (r=me, et, n-bu, ph and cy) and r2snl2 (r=me and n-bu). these complexes have been characterized by elemental analyses, ir, 1h-nmr, mass and mössbaure spectroscopy.

A variety of molybdenum or tungsten complexes that contain a tert-butylimido ligand have been prepared. For example, the o-methoxybenzylidene complex W(N-t-Bu)(CH-o-MeOC6H4)(Cl)2(py) was prepared through addition of pyridinium chloride to W(N-t-Bu)2(CH2-o-MeOC6H4)2, while Mo(N-t-Bu)(CH-o-MeOC6H4)(ORF)2(tBuNH2) complexes (ORF = OC6F5 or OC(CF3)3) were prepared through addition of two equivalents...

Electronic effects were investigated on the singlet–triplet energy gaps of divalent unsaturated seven- membered ring R2C6H6M (M=C, Si, Ge, Sn, Pb, R= –H, -CH3, i-Pr , t-Bu) at B3LYP/6-311++G** level. All the triplet states of R2C6H6C were more stable than the related the singlet states while all the singlet states of R2C6H6M (M= Si, Ge, Sn, Pb, R= –H, -CH3, i-Pr , t-Bu) were more stable than th...

Listening is regarded as an interactive process involving decoding of information. This study was launched to find out the impact of bottom-up (BU) and top-down (TD) techniques on Iranian lower and upper intermediate learners’ listening comprehension. We selected a total of 120 participants in six intact classes, three lower intermediate and three upper intermediate. The proficiency level of th...

The convenient five-coordinate starting materials, Salen((t)Bu)AlCl (Salen((t)Bu) = N,N'-alkylene (or arylene) bis (3,5-di-tert-butyl-2-hydroxybenzylideneamine) (1-4) can be used in a wide range of reactions to form five-coordinate aluminum compounds. Herein, these reagents were used to produce new five-coordinate azides, LAlN(3) (L = Salen((t)Bu) (5), Salpen((t)Bu) (6), and Salomphen((t)Bu) (7...

Este relato de experiência na Biblioteca Universitária da Universidade do Estado Santa Catarina tem por objetivo descrever as atividades desenvolvidas no projeto BU Capacita e mensurar o alcance das capacitações realizadas em 2020 2021. Surge questionamento: Quais foram os reflexos Capacita? Cientes transição paradigmas pelas quais Bibliotecas Universitárias (BUs) seus profissionais se deparara...

Chapter 1 The attempted syntheses of molybdenum imido alkylidene complexes of the type Mo(NArc,)(CH-t-Bu)[Biphen] and Mo(N-2-CF 3C6H4)(CHCMe 2Ph)[Biphen] (Biphen2 = 3,3'-di-t-butyl-5,5',6,6'-tetramethyl1,1'-biphenyl-2,2'-diolate) from Mo(NArcl)(CH-tBu)(OTf)2(dme) and [Biphen]K2 have sporadically afforded mixtures containing the desired products along with the corresponding amido alkylidyne comp...