Dispersive liquid-liquid microextraction (DLLME) and spectrofluorimetry, coupled with chemometrics methods, are proposed in this work for the pre-concentration and determination of ofloxacin concentration in spiked human urine. Chloroform and acetonitrile were selected as the extraction and dispersive solvents by the one-variable-at-a-time process. The Box-Behnken design was used to optimize th...

A method for the simultaneous spectrophotometric determination of nickel, cobalt and copper based on the formation of their complexes with 2-(2-Thiazolylazo)-p-Cresol (TAC) in micellar media of Triton X-100 is proposed. The absorbance spectra were recorded in the range of 500 to 800 nm. The linear concentration range for nickel, cobalt and copper in solution calibration sets were 0.05–1.80, 0.1...

a method for the simultaneous spectrophotometric determination of nickel, cobalt and copper based on theformation of their complexes with 2-(2-thiazolylazo)-p-cresol (tac) in micellar media of triton x-100 isproposed. the absorbance spectra were recorded in the range of 500 to 800 nm. the linear concentrationrange for nickel, cobalt and copper in solution calibration sets were 0.05–1.80, 0.10–6...

An analytical methodology based on spectrophotometric and partial least squares (PLS) algorithm for thesimultaneous determination of ampicillin and penicillin in human plasma was developed and validated. Themultivariate model was developed as a binary calibration model and it was built and validated with anindependent set of synthesis and real samples in presence of matrix. It is shown how a de...

The models were created using the Orthogonal Partial Least Squares (OPLS) method implemented in Simca-P+ 12 (Umetrics). This method was first introduced by Trygg et al., and is basically an extension of the Partial Least Squares (PLS) approach. It combines Orthogonal Signal Correction (OSC, an algorithm often applied in spectroscopic data analysis) with classical PLS regression. Using OPLS, the...

Online social capital (OSC) is of great significance to the sustainable development peasant e-entrepreneurs in era media. The objective this research was explore how acquire and utilize OSC through use This study proposes an analytical framework “social media behaviors–OSC–resource acquisition” including moderating effect offline capital. An empirical test conducted using data from 306 surveys ...

Objective. To explore the urinary biochemistry features of syndromes of traditional Chinese medicine (TCM) such as syndrome of stagnation of liver Qi, spleen deficiency, liver Qi stagnation, and spleen deficiency (LSSDS) in sub-optimal health status (SHS). Methods. 12 cases for each syndrome group in SHS were selected, 12 subjects were used as a normal control group, and (1)H NMR detection was,...

A method for the simultaneous spectrophotometric determination of nickel, cobalt and copper based on theformation of their complexes with 2-(2-Thiazolylazo)-p-Cresol (TAC) in micellar media of Triton X-100 isproposed. The absorbance spectra were recorded in the range of 500 to 800 nm. The linear concentrationrange for nickel, cobalt and copper in solution calibration sets were 0.05–1.80, 0.10–6...