this paper focused on a novel method of electroless plating ruthenium (ru) on solid or porous substrates like porous stainless steel (pss) discs or ceramic tubes. a novel complexing plating bath of ru was developed. it is proven that ru can be deposited directly on these substrates by the bath at a temperature of 328 k and strong alkaline environment. tga, sem, edx and xrd confirmed the success...

This paper presents a new gel combustion method to synthesize palladium nanoparticles, palladium oxide (PdO) nanoparticles and palladium-palladium oxide nanocomposites. In the proposed method, there are some effective parameters including palladium chloride concentration, polyvinyl alcohol (PVA) concentration, acid concentration, solvent composition and combustion temperature that their values ...

The elaboration of a polymeric catalytic membrane containing palladium nanoparticles is presented. The membrane was prepared using a photo-grafting process with imidazolium-based ionic liquid monomers as modifying agent and microPES as support membrane. Ionic liquid serves as a stabilizer and immobilizer for the catalytic species, i.e. palladium nanoparticles. The Suzuki–Miyaura cross-coupling ...

Early studies have focused on the synthesis of palladium nanoparticles within the periplasmic layer or on the outer membrane of Desulfovibrio desulfuricans and on the S-layer protein of Bacillus sphaericus. However, it has remained unclear whether the synthesis of palladium nanoparticles also takes place in the bacterial cell cytoplasm. This study reports the use of high-resolution scanning tra...

The aim of this work theoretical study is to theoretically investigate a inorganic membrane assisted purifcation process of an H2-rich stream derived from a conventional methanol steam reforming stage. In particular, a black-box model for multicomponent gas mixture purifcation is dev...

Among the unconventional approaches of supporting catalyst nanoparticles, layer-by-layer assembly polyelectrolyte multilayers for nanoparticle adsorption represents an easy and convenient method. It enables deposition singularly adsorbed nanoparticles prevents them from aggregating. In this work, polydopamine was grafted onto internal surface a Teflon AF-2400 tubular membrane, known its excelle...

Palladium holds a unique position among the metallic elements in being able to take into solution large quantities of hydrogen while simultaneously retaining a high degree of ductility. These attributes coupled with the high mobility or rate of diffusion of hydrogen in the lattice have been exploited in the use of palladium and subsequently of palladiumbased alloys as hydrogen diffusion membran...

A palladium membrane was prepared using the electroless plating technique (ELP) for the separation and purification of hydrogen from a gas mixture. Depending on operating conditions, hydrogen flux from the membrane was in the range of 0.012-0.023 mol.m-2.s-1. The membrane performance in the presence of CO2 was investigated. The results of the GC analysis showed that at a feed concentration of 1...

a palladium composite membrane was prepared via electroless plating technique using organic-inorganic method during activation process. the ceramic support surface was modified by two tio2-boehmite and one γ-alumina layers to avoid pd penetration in support pores. thin and defect-free pd composite membrane was obtained by creating a relative smoothness on the ceramic support and using pd nanopa...