Highly efficient PDMS based membranes with a new type of fluorinated MOF-808 were successfully prepared and used for the first time in pervaporation (PV). Two types ligands i.e. trifluoroacetic acid (TFA) pentafluoropropionic (PFPA) during MOF synthesis. These slightly different size chemical character influenced material properties membranes, roughness, contact angle, surface free energy, ther...

the effects of operating parameters such as feed temperature and permeate-side pressure on the performance of a commercial pva membrane in the dehydration of toluene by a pervaporation (pv) membrane system is studied in the present work. the results obtained indicate that increasing temperature in the range of 40 to 70 °c and reducing permeate pressure in the range of 1 to 10 mmhg increase memb...

As a well-known one-atom thick nanosheets with preeminent physicochemical properties, graphene and its derivatives (e.g., graphene oxide, GO) have shown great potential on the membrane separation filed. This paper presents an update of GO laminates developments, including the membrane preparation methods, physicochemical properties and water vapor transport of GO laminates, and their applicatio...

• PEBA thin-film composite hollow fiber were fabricated by coating. Pervaporation tests carried out with membranes of different active layer thicknesses. Good performance for recovery butanol from ABE mixtures. Membrane support has a relevant contribution to mass transfer resistance. This work reports the continuation previous efforts recover (acetone-butanol-ethanol) fermentation process perva...

Nanopore silicalite type membranes were prepared on the outer surface of a porous-mullite tube by in situ liquid phase hydrothermal synthesis. The hydrothermal crystallization was carried out under an autogenously pressure, at a static condition and temperature of 180 °C with tetrapropylammonium bromide (TPABr) as a template agent. The molar composition of the starting gel of silicalite zeolite...

In this work, ceramic hollow fiber supported polydimethylsiloxane (PDMS) composite membranes were developed by dip-coating PDMS layer on the surface of macroporous ceramic hollow fiber support. By controlling the properties of polymer solution and ceramic hollow fiber, high-quality ceramic hollow fiber supported PDMS composite membranes were fabricated for pervaporation (PV) recovery of biobuta...

BACKGROUND Biomass pretreatment using certain ionic liquids (ILs) is very efficient, generally producing a substrate that is amenable to saccharification with fermentable sugar yields approaching theoretical limits. Although promising, several challenges must be addressed before an IL pretreatment technology can become commercially viable. One of the most significant challenges is the affordabl...

A zeolite NaA (A-type zeolite of ca. 0.4 nm pore size; Linde Type A, LTA) membrane for the dehydration of alcohol was characterized by X-ray diffraction analysis (XRD). Also, the relationship between the X-ray absorption and the EtOH/H2O pervaporation (PV) dehydration performance (water selectivity and permeation flux) of the LTA membrane was first investigated. The LTA membranes used here were...

Abstract: Nano pore Mordenite membranes were prepared on the outer surface of ceramic tubular tubes via hydrothermal synthesis and evaluated for dehydration pervaporation of water unsymmetrical dimethylhydrazine UDMH mixtures. Highly water-selective mordenite membranes were prepared and the optimum reaction condition was found to be 24 h crystallization time and 170 °C crystallization temperatu...

Because of the emerging scarcity of oil resources and the demand for environmental protection, as a typical biofuel, biobutanol produced by biomass fermentation is critical for the development of renewable energy. Pervaporation is considered to be an attractive separation technology for both the recovery of butanol from fermentation broth and the dehydration of butanol from low-water content so...