With the present theoretical study of the photochemical switching of E-methylfurylfulgide we contribute an important step towards the understanding of the photochemical processes in furylfulgide-related molecules. We have carried out large-scale, full-dimensional direct semiempirical configuration-interaction surface-hopping dynamics of the photoinduced ring-closure reaction. Simulated static a...

We have developed a photochemical model of thrombotic middle cerebral artery (MCA) occlusion in the guinea pig for investigating factors contributing to the development of cerebral infarction. In this model, cyclic flow reductions (CFRs) after recanalization of the MCA are a common observation and might contribute to the development of cerebral infarction. Therefore, we sought to measure the ti...

The Sydney basin region experiences some high ozone episodes in summer, especially in the north west and south west of Sydney. Observation-based methods can be used to provide a means to access the potential extent of photochemical smog problem at various regions in the Sydney area. In this study, the observation-based Integrated Empirical Rates (IER) model is used to determine and understand t...

The bottom-up construction and operation of machines and motors of molecular size is a topic of great interest in nanoscience, and a fascinating challenge of nanotechnology. The problem of the energy supply to make molecular machines work is of the greatest importance. Research in the last ten years has demonstrated that light energy can be used to power artificial nanomachines by exploiting ph...

A model-based approach is here developed and applied to predict the long-term trends of indirect photochemical processes in the surface layer (5m water depth) of Lake Maggiore, NW Italy. For this lake, time series of the main parameters of photochemical importance that cover almost two decades are available. As a way to assess the relevant photochemical reactions, the modelled steady-state conc...

Photochemical interpretations of slow (opto-electronic) phenomena in CdS crystals are investigated theoretically and experimentally. It is seen that the presence of Ni impurity atoms has a major influence on some of these slow phenomena. Consequently, impurity atoms must be included in the considerations if a model for photochemical bulk reactions is to be developed. A non-photochemical interpr...