Self-assembly is a ubiquitous physicochemical phenomenon. It is inherent to molecular recognition effects in the biological domain, and thus presents a basis for understanding the constitution and dynamic organization of living beings. However, it is argued in this paper that the very notion of self-assembly presents an incorrect and misleading one for the physical effects that it stands for. S...

Natural minerals are widely used in treatment technologies as mineral fertilizer, food additive in animal husbandry, and cosmetics because they combine valuable ion-exchanging and adsorption properties together with unique physicochemical and medical properties. Saponite (saponite clay) of the Ukrainian Podillya refers to the class of bentonites, a subclass of layered magnesium silicate montmor...

The drug interaction between new quinolone antibiotics (NQs) and polyvalent metal cation products, leading to a significant decrease in the absorption of NQ, is considered to be attributable to the formation of poorly absorbable chelate and physicochemical adsorption of NQs to cation products. To clarify the mechanisms of this drug interaction in detail, we investigated the effects of Al(3+) or...

the dynamics of multicomponent adsorption in a fixed bed adsorber is examined numerically. the dynamic model of adsorption in the packed column included axial dispersion and variable space velocity along the bed for the multicomponent adsorption adsorption the pore fluid and the solid phase are in equilibrium with a nonlinear isotherm. the numerical solution is based upon the modified lax-wendr...

An adsorbent prepared by entrapping active carbon derived from the stems of Achyranthes aspera plant in the calcium alginate beads (CABAA) has been investigated for its adsorption nature towards the removal of phosphate by varying various physicochemical parameters. Surface morphological studies are made using FTIR, XRD, FESEM, and EDX. The sorption mechanism is analyzed using Freundlich, Langm...

Based on the adsorption performance of composite microspheres with activated carbon (AC) and sodium alginate (SA), as well as the magnetic property of Fe₃O₄, we designed and explored an efficient strategy to prepare a unique, multifunctional Fe₃O₄/AC/SA composite absorbent (MSA-AC) that extracted dye from aqueous solution. The composite exhibited the following advantages: rapid and simple to pr...

This review describes different strategies of surface elaboration for a better control of biomolecule adsorption. After a brief description of the fundamental interactions between surfaces and biomolecules, various routes of surface elaboration are presented dealing with the attachment of functional groups mostly thanks to plasma techniques, with the grafting to and from methods, and with the a...

An air-cathode MFC-adsorption hybrid system, made from earthen pot was designed and tested for simultaneous wastewater treatment and energy recovery. Such design had demonstrated superior characteristics of low internal resistance (29.3Ω) and favor to low-cost, efficient wastewater treatment and power generation (55mW/m(3)) with average current of 2.13±0.4mA. The performance between MFC-adsorpt...

An environmentally benign and efficient hydrothermal reduction method was applied for the preparation of three-dimensional (3D) porous graphene hydrogel (GH) adsorbents. The physicochemical properties of GH granules were systematically characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), Raman spectra and Brunauer-Emmett-Teller (BET) method. GH granules showed an ex...

Membranes grafted with water-soluble polymers resist protein adsorption and adhesion to cellular surfaces. Liposomes with surface-grafted polymers therefore find applications in drug delivery. The physicochemical properties of polymer-grafted lipid membranes are reviewed with mean-field and scaling theories from polymer physics. Topics covered are: mushroom-brush transitions, membrane expansion...