One dimensional polyaniline nanowire is an electrically conducting polymer that can be used as an active layer for sensors whose conductivity change can be used to detect chemical or biological species. In this review, the basic properties of polyaniline nanowires including chemical structures, redox chemistry, and method of synthesis are discussed. A comprehensive literature survey on chemires...

Polyaniline is known to be a true metal, though a nanometal. Previous experimental and theoretical evidence is reviewed. Two important structural features are presented, which have not publicly been discussed so far: (a) The formation of complexes between polyaniline and metals (Cu, Fe, Zn, In, etc.) which are crucial for most practical applications of the organic metal, polyaniline; and (b) a ...

In the field of inherently conducting polymers, polyaniline (Pani) has elicited tremendous interest due to its promising electrical properties and unique redox tunability. Synthetic routes involving the use of polyelectrolytes have significantly improved the processability of polyaniline. Recently, a template guided synthesis catalyzed by an enzyme, horseradish peroxidase (HRP), has provided a ...

Friction Nanolithography (FRNL) is used to fabricate polyaniline nano-wire on a flexible, insulating, and highly transparent substrate. FRNL uses SPM tip to scratch the substrate to form a trench with higher friction force. Polyaniline nano-wire is selectively deposited on the trench. Sub-100 nm polyaniline wire is fabricated based on FRNL.

Stabilizer-free polyaniline nanofiber aqueous colloids were obtained by the direct dispersing of polyaniline nanofiber prepared in the presence of β-cyclodextrin. The polyaniline nanofiber, the diameters of which are between 80 and 100 nm, can be steadily dispersed in near neuter (pH=6.5) aqueous solution for about 60 days without any steric or electrostatic stabilizer. © 2007 Elsevier B.V. All...

absorptive characteristics of polyaniline synthesized in different solvents were studied. water and mixture of water with other solvents were implemented for polyaniline synthesis. synthesized polyanilines in powder shape is used as an adsorbent to remove toxic hexavalent chromium from aqueous solutions. experiments were conducted in batch mode. removal mechanism involving polyaniline is the co...

Polyaniline/ZnO nanocomposite thin films were prepared via an electrochemical synthesis route on ITO coated glass substrates. ZnO nanoparticles were uniformly dispersed in to the polyaniline matrix. Interaction between ZnO nanoparticle and polyaniline has been studied using X-ray diffraction (XRD), UV-Vis absorption spectroscopy, PL spectroscopy, AFM and I-V characteristics. The ammonia gas sen...

This study investigates the effect on: (1) the bulk surface and (2) the three-dimensional non-woven microfabric scaffolds of poly(N-isopropylacrylamide)-CNT-polyaniline on growth and viability of cells. The poly(N-isopropylacrylamide)-CNT-polyaniline was prepared using coupling chemistry and electrospinning was then used for the fabrication of responsive, non-woven microfabric scaffolds. The el...

A hybrid quantum mechanics (QM)/molecular dynamics (MD) simulation is performed to investigate the effect of an ionizable group (-SO₃(-)Na⁺) on polyaniline as gas sensing materials. Polymers considered for this work include emeraldine base of polyaniline (EB-PANI) and its derivatives (Na-SPANI (I), (II) and (III)) whose rings are partly monosubstituted by -SO₃(-)Na⁺. The hybrid simulation resul...

Eight persons from five institutions in different countries carried out polymerizations of aniline following the same preparation protocol. In a “standard” procedure, aniline hydrochloride was oxidized with ammonium peroxydisulfate in aqueous medium at ambient temperature. The yield of polyaniline was higher than 90 % in all cases. The electrical conductivity of polyaniline hydrochloride thus p...