Krasol® polybutadiene diols are anionically polymerized products characterized by very narrow molecular weight distribution, linear structure of polymer chains and the absence of species with functionality higher than 0.2. These unique features make them suitable as hydrophobic polyol components for use in thermoplastic polyurethanes (TPUs). Various TPU formulations were developed using polybut...

Rubber composite fibers containing silver nanoparticles with high morphological stability were prepared through combination of electrospinning and in-situ chemical crosslinking. The composite fibers included those of Ag/polybutadiene rubber (BR), Ag/polyisobutylene-isoprene rubber (IIR), and Ag/silicon rubber (SiR). During the study, Ag nanoparticles (Ag NPs) were first generated through reduci...

We report a comparison of high resolution inelastic x-ray Brillouin scattering to coherent inelastic neutron scattering for amorphous deuterated polybutadiene, done for one temperature in the glass phase and another one in the melt. The x-ray scattering proves to be by far the better technique for such a polymer within its present resolution bounds. The neutron scattering allows one to extend t...

Plasmonic materials currently have a plethora of applications. How would dielectric matrix, such as diblock copolymers, tune plasmonic properties? In this work, self-assembled gold nanoparticles were fabricated in medium vacuum conditions on heated Corning glass substrates (kept at 440 °C) under the coexistence argon and air by means DC magnetron sputtering. These samples compared structurally ...

Catalytic cyclopropanation of commercial 1,2or 1,4cis-polybutadiene, respectively, with ethyl diazoacetate catalyzed by [TpCu(NCMe)] (Tp 1⁄4 hydrotris(3,4,5-tribromo-1-pyrazolyl)borate) at room temperature afforded high molecular weight (Mn > 10 5 mol ) side-chain or main-chain, respectively, carboxyethyl cyclopropyl-substituted polymers with variable and controlled degrees of functionalization...

This communication presents a determination of the glass transition of polybutadiene under very high pressure, and raises the problem of the determination of the relative effects of temperature and density on the glass transition, depending on the pressure and temperature conditions. Local structure and slow dynamics were studied, by neutron scattering and calorimetry. To the best of our knowle...

The homogeneous non-catalytic hydrogenation of cis-1,4 poly(isoprene), isotactic cis-1,4 poly(1,3-pentadiene) and syndiotactic cis-1,4 poly(1,3-pentadiene) with diimide, formed by thermal decomposition of para-toluenesulfonylhydrazide, is examined. Perfectly alternating ethylene/propylene copolymers having different tacticity (i.e., isotactic and syndiotactic), which are difficult to synthesize...

cis-polybutadiene was functionalized using in–situ generated dmd as oxidant and tetra-n-butyl ammonium bromide as phase transfer catalyst (ptc). the epoxidation process was investigated by 1hnmr spectroscopy. 1hnmr spectrum analysis of products confirms the absence of ring opening side products in epoxidation reaction. various factors such as reaction temperature, reaction time and the concentr...