We employ the dynamic extension of self-consistent field theory (DSCFT) to study dynamics and order–disorder transitions (ODT) in AB diblock copolymer binary mixtures of two different monodisperse chain lengths by imitating the dynamic storage modulus G0 corresponding to any given morphology in the oscillatory shear measurements. The different polydispersity index (PDI) is introduced by binary ...

Multiobjective Pareto optimal solutions for epoxy semi-batch polymerization process are obtained by adapting nondominated sorting genetic algorithm II (NSGA II). The objective is to produce polymer of maximum possible number average molecular weight (Mn) with a specified value of polydispersity index (PDI) and number average molecular weight in minimum possible time. The M and reaction time a p...

the aim of this work was to investigate the influence of interactions between modified starch (hi-cap 100) and the nonionic surfactant tween 80 on the properties of cardamom oil-in-water emulsion and its corresponding spray dried microcapsules. to this end the mean diameter and size distribution of droplets as well as their polydispersity index and also the viscosity and flow behavior of emulsi...

A detailed model was developed for the emulsion copolymerization of styrene and MMA to predict the evolution of the particle size distribution (PSD) and molecular weight distribution (MWD) over the entire range of monomer conversion. A system exhibiting zero-one kinetics was employed. The model was used to optimise the emulsion copolymerization process in order to maximize particle size polydis...

Polymeric stabilizers have received attention in the preparation of nanostructured systems due to their ability to enhance formulation stability. Considering this, the objective of this work was to prepare poly(ε-caprolactone) nanocapsules using the pullulan as a polymeric stabilizer. The nanocapsules were prepared using the interfacial deposition method of preformed polymers and they were char...

Enteric coated formulations protect drugs from degrading in the harsh environment of the stomach (acidic pH and enzymes), and promotes drug delivery to and absorption into the duodenum and/or later parts of the intestine. Four DoE models were applied to optimize formulation parameters for the preparation of pH sensitive nifedipine nanoparticles. Stability studies were performed on the optimized...

This work reports that the rheology of ideally monodisperse lambda ( λ $$ \lambda ) phage DNA solutions is extremely sensitive to applied strain in dynamic oscillatory experiments. exhibits nonlinearity at strains far smaller than what observed conventional synthetic polymers. However, it found polydisperse calf thymus does not exhibit extreme sensitivity. By mixing samples with DNA, we correla...

Submit Manuscript | http://medcraveonline.com Abbreviations: PLGA: Poly Lactic-Co-Glycolic Acid; PEG: Polyethylene Glycol; FDA: Food and Drug Administration; AlgPLGANP: Alginate-PLGA Nanoparticle; PDI: Polydispersity Index; TRF: Tocotrienol Rich Fraction; FA: Folic Acid; α: Alpha; ZP: Zeta Potential; SEM: Scanning Electron Microscopy; PXRD: Powder X ray Diffraction; DSC: Differential Scanning C...

Recent simulations predict that aggregating nanospheres functionalized with polymer "tethers" can self-assemble to form a cylinder, perforated lamellae, lamellae, and even the double gyroid phase, which are phases also seen in block copolymer and surfactant systems. Nanoparticle size polydispersity is likely to be a characteristic of these systems. If too high, polydispersity may destabilize a ...