Ramanand IR-spectra of four compounds of the general composition TlelöMj/",, (I4) \n: formal valence of the M-atom, M = Ag, Au, Pb and (Bio.sTlo.s)] were investigated in order to identify the polyiodide species present. In accordance with structural results comparable amounts of l4 2 and l3~/I~-groups were found for M = Ag, Pb and (Bio.sTlo.s), while in Tl6l6Au2(Li) I3_/I~groups predominate.

Foundations of the discording vocabulary novel supramolecular interactions lay onto polyiodide chemistry. Reviewing advancements in field, we tackle I?I contacts understanding, rationalization, and language on semantic scientific grounds.

the regioselective ring opening of styrene oxide using elemental iodine and bromine in the presence of disulfides as new catalysts was studied. the conductivity titration and uv spectroscopy were used to study the interaction of iodine with these catalysts. the results indicate that disulfide 11 is efficient in polyiodide formation, and can catalyze this reaction in excellent yield and high reg...

Iodine-dense polyiodide phases are interesting materials for a number of potential uses, including batteries and solid-state conductors. The incorporation transition metal cations is considered promising way to enhance the stability, tune properties, influence architecture polyiodides. However, several metals, Cu(II), may suffer redox processes, which generally make them not compatible with I2/...