The adhesive interactions of block copolymers composed of poly(methyl methacrylate) (PMMA)/poly(acrylic acid) (PAA) and poly(methyl methacrylate)/poly(2-hydroxyethyl methacrylate) (PHEMA) with the proteins fibronectin, bovine serum albumin and collagen were studied by atomic force microscopy. Adhesion experiments were performed both at physiological pH and at a slightly more acidic condition (p...

The incorporation of self-assembled nanoparticles, a.k.a. hydroxylated nanoballs, into poly(2-hydroxyethyl methacrylate)(PHEMA) gives rise to a cross-linked network/hydrogel with enhanced interfacial interaction, whereas its inclusion in poly(methyl methacrylate)(PMMA) results in plasticization.

We report on the grafting of poly(methyl methacrylate) (PMMA) onto the surface of high-density functionalized graphene oxides (GO) through controlled radical polymerization (CRP). To increase the density of surface grafting, GO was first diazotized (DGO), followed by esterification with 2-bromoisobutyryl bromide, which resulted in an atom transfer radical polymerization (ATRP) initiator-functio...

Poly(methyl methacrylate) (PMMA) stabilized colloidal metallic iron nanoparticles without additional surfactant or stabilizer were fabricated by a wet chemical reduction method. The synthesized colloidal iron nanoparticles were found to be stable in tetrahydrofuran (THF) solution and the dried PMMA–Fe nanocomposites were ferromagnetic even at room temperature as illustrated by magnetometer meas...

The poly(methyl methacrylate) (PMMA)/poly(methyl methacrylate)–poly(methyl acrylate acid) copolymer (PMMA–PMAA) composite polymer latex were synthesized by the method of soapless seeded emulsion polymerization. The morphology of the composite polymer latex was core–shell structure. The core was PMMA and shell was PMMA–PMAA copolymer. Because the PMMA–PMAA copolymer was shell, the carboxylic aci...

Waveguides made of poly-methyl-methacrylate (PMMA) play a major role in the homogeneous distribution of display backlights as a matrix for solid-state dye lasers and polymer optical fibers (POFs). PMMA is favored because of its transparency in the visible spectrum, low price, and well-controlled processability. Nevertheless, technical drawbacks, such as its limited temperature stability, call f...

The effect of Candida albicans biofilms and methyl methacrylate (MMA) pretreatment on the bond strength between soft denture liners and polymethyl methacrylate (PMMA) resin was analyzed. Specimens were prepared and randomly divided with respect to PMMA pretreatment, soft liner type (silicone-based or PMMA-based), and presence or absence of a C. albicans biofilm. Samples were composed of a soft ...

Carbon nanospheres with a high Brunauer-Emmett-Teller (BET) specific surface area were fabricated via the pyrolysis of polyacrylonitrile-poly(methyl methacrylate) (PAN-PMMA) core-shell nanoparticles. Firstly, PAN-PMMA nanoparticles at high concentration and low surfactant content were controllably synthesized by a two-stage azobisisobutyronitrile (AIBN)-initiated semicontinuous emulsion polymer...

The low-energy vibrational density of states (VDOS) of hydrogenated or deuterated poly(methyl methacrylate) (PMMA) plasticized by dibutyl phtalate (DBP) is determined by inelastic neutron scattering. From experiment, it is equal to the sum of the ones of the PMMA and DBP components. However, a partition of the total low-energy VDOS among PMMA and DBP was observed. Contrary to Raman scattering, ...

Purpose: A radiopaque self-polymerizing adhesive resin was prepared by incorporating bismuth subcarbonate-poly(methyl methacrylate) prepolymerized composite (BS-PMMA) into an acrylic resin. The purpose of this study to evaluate the radiopacity resins.Methods: As a component, containing 50% subcarbonate used, and other metal compounds were adopted as controls. They added finely pulverized PMMA. ...