The recently developed protocol for the absolute determination of the various polysulfide species based by 1H NMR was applied to monitor the amount of such ions in alkaline media produced at different conditions. The thermal stability of each individual polysulfide species was also evaluated in temperature ranges representative of a typical alkaline pulping process. Overall, the species, S1, S2...

When an elastomer imbibes a solvent and swells, a force is generated if the elastomer is constrained by a hard material. The magnitude of the force depends on the geometry of the constraint, as well as on the chemistry of the elastomer and solvent. This paper models an elastomer crosslinked on the exterior surface of a metallic tubing. The elastomer then imbibes a solvent and swells. After the ...

This paper describes a new approach to site-selective sulfuration at the corner sites of Ag nanocrystals including triangular nanoplates and nanocubes. The reaction simply involved mixing an aqueous suspension of the Ag nanocrystals with an aqueous solution of polysulfide at room temperature. As a precursor to elemental S, polysulfide is highly soluble in water and can directly react with eleme...

Lithium metal has shown great promise as an anode material for high-energy storage systems, owing to its high theoretical specific capacity and low negative electrochemical potential. Unfortunately, uncontrolled dendritic and mossy lithium growth, as well as electrolyte decomposition inherent in lithium metal-based batteries, cause safety issues and low Coulombic efficiency. Here we demonstrate...

Lithium-sulfur batteries are highly promising for electric energy storage with high energy density, abundant resources and low cost. However, the battery technologies have often suffered from a short cycle life and poor rate stability arising from the well-known "polysulfide shuttle" effect. Here, we report a novel cell design by sandwiching a sp(3) boron based single ion conducting polymer ele...

Self-Healing Polymer: Effect of the Disulfide/Polysulfide Ratio” Marianella Hernańdez Santana,*,†,‡ Antonio M. Grande,† Sybrand van der Zwaag,† and Santiago J. García† †Novel Aerospace Materials Group, Faculty of Aerospace Engineering, Delft University of Technology, Kluyverweg 1, 2629 HS Delft, The Netherlands ‡Institute of Polymer Science and Technology (ICTP-CSIC), Juan de la Cierva 3, 28006...

A polysulfide material was synthesized by the direct reaction of sulfur and d-limonene, by-products of the petroleum and citrus industries, respectively. The resulting material was processed into functional coatings or molded into solid devices for the removal of palladium and mercury salts from water and soil. The binding of mercury(II) to the sulfur-limonene polysulfide resulted in a color ch...

The use of elastomer additives to solve the problems in oil well cementing has been investigated in recent years by several research groups in the petroleum industry. This study includes the laboratory examination of the effect of elastomer additives on the physical properties of heavy-weight oil well cement. In the research process, a candidate well is selected and the properties of the cement...

In order to properly model the friction and wear of elastomer materials, it is essential to understand some specific mechanical and tribological features. Mechanical characteristics of elastomer materials are different from those of metals and other relatively hard materials. Elastomers can bear large deformations, the stress-strain curves are non-linear, time and temperature dependent. When th...