Membrane rejection models generally neglect the effect of the pore entrance on intrapore particle transport. However, entrance effects are expected to be particularly important with ultrathin membranes, where membrane thickness is typically comparable to pore size. In this work, a 2D model was developed to simulate particle motion for spherical particles moving at small Re and infinite Pe from ...

When a fluid that undergoes a vapor to liquid transition in the bulk is confined to a long cylindrical pore, the phase transition is shifted (mostly due to surface effects at the walls of the pore) and rounded (due to finite size effects). The nature of the phase coexistence at the transition depends on the length of the pore: for very long pores, the system is axially homogeneous at low temper...

The influence of stabilizing hydrostatic pressure gradients on the drainage of a fractal porous medium is studied. The invasion process is treated with invasion percolation (IP) in a gradient. Fractality is mimicked by randomly closing bonds of a network. Two length scales govern the problem: the characteristic length of the pore structure xi(s) and a length scale xi(g) above which buoyancy det...

We present spatial distributions for pore path length and coordination number, pore throat size and nodal pore volume obtained for a 1:53 mm3 volume of 12.1% porosity Fontainebleau sandstone. The sandstone was imaged using Synchrotron X-Ray computed microtomography at 6 micron resolution. The spatial distributions were computed based upon three dimensional medial axis analysis of the void space...

Three mathematical models (mixed side-pore and profile side-pore diffusion with uniform or distributed pore length) are derived in dimensionless form to simulate the transport of solutes through the flowing channels and the stagnant pores of an unsaturated heap. Model parameters are determined from experimental tracer residence time distributions using the least square minimization approach. It...

A study of reflective interference spectroscopy [RIfS] properties of nanoporous anodic aluminium oxide [AAO] with the aim to develop a reliable substrate for label-free optical biosensing is presented. The influence of structural parameters of AAO including pore diameters, inter-pore distance, pore length, and surface modification by deposition of Au, Ag, Cr, Pt, Ni, and TiO2 on the RIfS signal...

We investigate the dynamics of polymer translocation through a nanopore under an externally applied field using the two-dimensional fluctuating bond model with single-segment Monte Carlo moves. We concentrate on the influence of the field strength E, length of the chain N, and length of the pore L on forced translocation. As our main result, we find a crossover scaling for the translocation tim...

We investigate the dynamics of polymer translocation through a nanopore under an externally applied field using the 2D fluctuating bond model with single-segment Monte Carlo moves. We concentrate on the influence of the field strength E, length of the chain N, and length of the pore L on forced translocation. As our main result, we find a crossover scaling for the translocation time τ with the ...

We investigate unforced and forced translocation of a Rouse polymer (in the absence of hydrodynamic interactions) through a silicon nitride nanopore by three-dimensional Langevin dynamics simulations, as a function of pore dimensions and applied voltage. Our nanopore model consists of an atomistically detailed nanopore constructed using the crystal structure of β-Si(3)N(4). We also use realisti...