Single-crystal X-ray structure analysis revealed the precise of a Ce-encapsulated Preyssler-type phosphotungstate which was first synthesized by Pope et al. Antonio reported that encapsulated Ce has 3+ oxidation state and is redox-inactive, unlike other Ce-containing phosphotungstates. Therefore, structural about position needed. The located in one side cavities, coordinated to H2O molecule. si...

The complex was prepared with preyssler polyoxoanion and transition metal (Mo), a cationic surfactant as connector. It has tuneable physical chemical potential which been exploited to study novel properties. A new technique of shock wave impulses is also used on the Mo-PHP complex. Extensive use surfactants could impact accumulation in environment set off surfacing bacterial resistance. Due ele...

The exploration of composition–structure–function relationship in proton-conducting solids remains a challenge materials chemistry. Polyoxometalate-based compounds have been long considered as candidates for proton conductors; however, their low structural stability and large decrease conductivity under reduced relative humidity (RH) limited applications. To overcome such limitations, the hybri...