The solute-solvent interactions of L-Cysteine and L-Methionine have been studied pH metrically in various concentrations (0.060.0% v/v) 1, 4-Dioxane-water mixture maintaining an ionic strength of 0.16 mol L-1 at ambient conditions. The protonation constants have been calculated with the computer program MINIQUAD75 and the best fit chemical models are selected based on statistical parameters. Li...

An explicit application of isodesmic reaction (a proton exchange between the studied and similar in structure reference molecule), where the free energy change of the protonation reaction in water was obtained using the free energies in solution from a single continuum model, was used to predict stepwise protonation constants of nitrilotriacetic acid. Calculations were performed at the RB3LYP/6...

The solubility of CO2 in the primary, secondary, tertiary and sterically hindered amine aqueous solutions at various conditions was studied. In the present work, the Modified Kent-Eisenberg (M-KE), the Extended Debye-Hückel (E-DH) and the Pitzer models were employed to study the solubility of CO2 in amine aqueous solutions. Two explicit equations are presented to evalu...

The protonation constants of new group of peptidomimetic cyclophanes with valine or phenylalanine moieties incorporated into the macrocyclic skeleton as well as their linear analogues were determined by potentiometric measurements in solutions of methanol-water mixtures at 25°C and constant ionic strength. The influence of cavity size, location of protonation sites, and attached substituents of...

The protonation constants of L-Aspartic acid have been studied pH-metrically in various concentrations (0-60% v/v) of acetonitrile- and ethylene glycol-water mixtures maintaining an ionic strength of 0.16 mol L-1 at 303K. The protonation constants have been calculated with the computer program MINIQUAD75 and are selected based on statistical parameters. Linear variation of step-wise protonation...

the protonation constant values of salicylic and 5-nitrosalicylic acid werestudied by a combinationof spectrophotometric and potentiometric methods at 25 °c in wide range of ionic strength. the ionicstrength of solutions was kept constant by sodium perchlorate as background electrolyte at 0.10 to 3.0 moldm-3. potentiometer was calibrated according to gran method at each of ionic strength. the p...

Equilibria of the reaction of molybdenum(VI) with L-aspartic acid (Asp) and L- Glutamic acid(Glu) have been studied by spectrophotometric measurements in mixed solvent systems at an ionicstrength of 0.2 mol/dm3 sodium perchlorate, employed (15, 20, 25, 30± 0.1°C) at pH ranges of 3.2to 5.5 with a high ratio of ligand to metal. The stability constants of the complexes and theresulting free energy...

the solubility of co2 in the primary, secondary, tertiary and sterically hindered amine aqueous solutions at various conditions was studied. in the present work, the modified kent-eisenberg (m-ke), the extended debye-hückel (e-dh) and the pitzer models were employed to study the solubility of co2 in amine aqueous solutions. two explicit equations are presented to evaluate the concentration of h...

the formation constants of the species formed in the systems h+ + cytidine 5
-monophosphate (cmp)and h+ + cytidine 5
-monophosphate + tl (i) ion have been determined in aqueous solution in a wideph range of 1.5 to 10.5 at 25 °c and different ionic strengths ranging from 0.1 to 1.5 moldm-3naclo4, nano3, and nacl using potentiometric-spectrophotometric technique. the composition ofthe complexes w...