نتایج جستجو برای: quadrupole coupling

تعداد نتایج: 160340  

1999
K. Egawa M. Masuzawa

Most of the quadrupole magnets in the KEK B-factory are accompanied by a set of vertical and horizontal dipole corrector magnets in both the LER and HER rings[1]. The typical separation between a quadrupole and a dipole corrector magnet is 202 mm, as measured from the laminated ends. This corresponds to ~3.7 (2.4) times of the bore radius of a quadrupole magnet in the arc (straight) sections. S...

1992
Carla Buzano Alessandro Pelizzola

The Blume Emery Griffiths model is investigated by use of the cluster variation method in the pair approximation. We determine the regions of the phase space where reentrant phenomenon takes place. Two regions are found, depending on the sign of the reduced quadrupole quadrupole coupling strength ξ. For negative ξ we find Para-Ferro-Para and Ferro-Para-Ferro-Para transition sequences; for posit...

2012

The nuclear quadrupole resonance of 14N was observed in KoPt(SCN)6 and K2Hg(SCN)4 at various temperatures. Both compounds yield large asymmetry parameters indicating the existence of asymmetric ^-electron distribution about a CN bond axis. The ionic character of metal-ligand bonds in the platinum and mercury complexes is estimated to be 28% and 58 %, respectively. The temperature dependence of ...

Journal: :The journal of physical chemistry. B 1999
C V Grant W Cope J A Ball G G Maresch B J Gaffney W Fink R D Britt

The aqueous vanadyl ion ([VO(H(2)O)(5)](2+)) has been investigated by X-band EPR, 94 GHz W-band EPR, and ESE-ENDOR. These experiments reveal information about the hyperfine (|A(xx)| = 208.5 MHz, |A(yy)| = 208.5 MHz, |A(zz)| = 547.0 MHz), and nuclear quadrupole coupling (|e(2)qQ| = 5.6 MHz) of the (51)V nucleus. The measured nuclear quadrupole coupling parameters are compared to values determine...

2013
P. MACHMER

From a consideration of odd-even intramolecular electron transfer processes in octahedrally co-ordinated transition metal complexes, two relationships have been derived. The first correlation describes 71 —> y3 optical electron transfer bands of the complexes K20sC l6 , K2IrCl6 , K2PtCl6 , K2PtCl4 as a function of the respective 35C1 nuclear quadrupole coupling constants. The second rela­ tions...

2010

The vertical beam spread is one of the most important parameters for the high brilliance storage ring, which is represented by the coupling ratio of the horizontal and vertical beam emittances. The coupling between the horizontal and vertical betatron oscillations and the vertical dispersion with the energy spread generate the vertical beam spread, so that they should be corrected. The latter h...

Journal: :The Journal of chemical physics 2005
Peter Schwerdtfeger Radovan Bast Michael C L Gerry Christoph R Jacob Martin Jansen Vladimir Kellö Anja V Mudring Andrzej J Sadlej Trond Saue Tilo Söhnel Friedrich E Wagner

An attempt is made to improve the currently accepted muonic value for the 197Au nuclear quadrupole moment [+0.547(16)x10(-28) m2] for the 3/2+ nuclear ground state obtained by Powers et al. [Nucl. Phys. A230, 413 (1974)]. From both measured Mossbauer electric quadrupole splittings and solid-state density-functional calculations for a large number of gold compounds a nuclear quadrupole moment of...

Journal: :The Journal of chemical physics 2004
Chakree Tanjaroon Kristen S Keck Stephen G Kukolich Michael H Palmer Martyn F Guest

The first rotational spectrum of a dinuclear complex, MnRe(CO)(10), has been obtained using a high-resolution pulsed beam microwave spectrometer. Sixty-four hyperfine components of the J=11-->J(')=12 and J=12-->J(')=13 rotational transitions were measured for two rhenium isotopomers. The B values obtained from the experiment are B=200.36871(18) MHz for the (187)Re isotopomer and B=200.5561(10) ...

2003
Gang Wu Alan Wong Suning Wang

We report solid-state 25Mg NMR, X-ray crystallographic, and quantum-mechanical calculation results for bis(pyridine)(5,10,15,20-tetraphenylporphyrinato)magnesium(II), Mg(TPP)·Py2. Mg(TPP)·Py2 crystallizes in the triclinic form, in the space group P1. The unit cell parameters are: a = 9.6139(13) Å, b = 11.0096(16) Å, c = 11.8656(15) Å; α = 102.063(3)°, β = 103.785(3)°, γ = 114.043(2)°; Z = 1. Th...

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