The aim of this work is to synthesise chitosan and N-vinylimidazole graft-copolymers various compositions study the properties their aqueous solutions.Chitosan were obtained by solution polymerisation in presence a ceric ammonium nitrate redox initiator. synthesised graft copolymers characterised FTIR determine grafted side chains poly-N-vinylimidazole gel permeation chromatography molecular wi...

Modification of natural polymers like protein by graft co-polymerization is an important method to incorporate the desired properties into the backbone. Soy protein concentrate (SPC) was grafted with ethylmethacrylate (EMA) using ascorbic acid /potassium persulphate as redox initiator system under pressure. Different reaction parameters such as reaction time, reaction pressure, solvent amount, ...

Abstract Due to the shortage of high-quality natural sand, development polycarboxylic acid water reducer with excellent clay resistance has become a research hotspot in recent years. Using acrylic acid, methyl 4-vinylbenzoate, ethylene glycol monovinyl polyethylene ether molecular weight 3000 (EPEG-3000) as comonomers, under action sodium bisulfite formaldehyde-hydrogen peroxide redox initiator...

Introduction Graft copolymerization is one of the most promising technique uses to modify the properties of naturally available polymers with a minimum loss in their native characteristics. Methods and Materials Graft copolymerization is a very significant technique to add hybrid properties in backbone of polymers. The grafting generally initiated through the formation of free radical centers...

1. Unsubstituted 6-membered aromatic ring systems (fused, unfused, or mixed) chrysene mutagenic initiator carcinogenic pyrene co-carcinogen mutagenic benzo[a]pyrene mutagenic carcinogenic fetotoxic teratogenic benzo[e]pyrene carcinogenic mutagenic benzo[a]anthracene mutagenic carcinogenic benzo[c]phenanthrene initiator mutagenic naphthalene inhibitor phenanthrene initiator mutagenic anthracene ...

Electrochemically mediated atom transfer radical polymerization (eATRP) of styrene was studied in detail by using CuBr2/TPMA (TPMA = tris(2-pyridylmethyl)amine) as a catalyst. Redox properties various Cu(II) species were investigated CH3CN, dimethylformamide (DMF), and dimethyl sulfoxide (DMSO) both the absence presence 50% (v/v) styrene. This investigation together with preliminary eATRP exper...

Many security protocols have the aim of authenticating one agent acting as initiator to another agent acting as responder and vice versa. Sometimes, the authentication fails because of executing several parallel sessions of a protocol, and because an agent may play both the initiator and responder role in parallel sessions. We take advantage of the notion of transition systems to specify authen...

In this study, stable lattices of terpolymer butyl acrylate, methyl methacrylate, and styrene were synthesized by a mini-emulsion polymerization technique using tert-butyl hydroperoxide TBHP/Fe2 /ethylenediaminetetraacetic acid/sodium formaldehyde sulfoxylate redox initiators at room temperature, and the kinetics of the reaction were studied. The reaction rate was obtained from periodic samplin...