in this work, quantitative structure-property relationship (qspr) approaches were used to predict the redox potential of 42 phenolic antioxidants. the structures of all compounds optimized by the am1 semi-empirical method and then a large number of molecular descriptors were calculated for each compound in the data set. subsequently, stepwise multilinear regression was applied to select the mos...

Using microflotation method, this study explored the collectorless flotation of Chalcocite and its dependence on the redox potential of pulp . Electrochemical studies were performed by cyclic voltammetry  in specific potential ranges and at different pH values. The results show that significant floatability of Chalcocite occurs in the specific reducing conditions. By increasing potentials, on t...

Redox potential, known as oxidation–reduction or oxidoreduction potential (ORP), not only indicates the reduction and oxidation capacity of the environment but also reflects the metabolic activity of microorganisms. Redox potential can be monitored online and controlled in time for more efficient fermentation operation. This chapter reviews the enzymes that modulate intracellular redox potentia...

The aqueous electrochemistry of a number of anthraquinone derivatives was studied by using cyclic voltammetry at the surface of carbon paste electrode (CPE). From measurements of the half-wave potential as a function of pH, the potential - pH diagrams were constructed for each compound. The values of formal potentials and the pK'a of some different redox and acid-base couples inv...

the aqueous electrochemistry of a number of anthraquinone derivatives was studied by using cyclic voltammetry at the surface of carbon paste electrode (cpe). from measurements of the half-wave potential as a function of ph, the potential - ph diagrams were constructed for each compound. the values of formal potentials and the pk'a of some different redox and acid-base couples involved in each c...

The redox behavior cobalt chloride was studied voltammetrically in presence and absence of L- Carrageenan (LK) natural polymer using glassy carbon electrodes in 0.1 M KCl supporting electrode. Scan rates are studied for the redox behaviors for CoCl2 alone or in presence of L- Carrageenan (LK) natural polymer. Stability constants for the interaction of cobalt ions with L - Carageenan (LK) natura...

Reactive oxygen species (ROS), including superoxide anion, hydroxyl radicals and hydrogen peroxide, can be formed endogenously by incomplete reduction of molecular oxygen occurring during mitochondrial oxidative phosphorylation, or by interactions with exogenous sources. The antioxidant defense system, with its major enzymes Catalase, superoxide dismutase (SODs) and glutathione peroxidase (Gpx)...

Organic molecules are currently investigated as redox species for aqueous low-cost redox flow batteries (RFBs). The envisioned features of using organic redox species are low cost and increased flexibility with respect to tailoring redox potential and solubility from molecular engineering of side groups on the organic redox-active species. In this paper 33, mainly quinone-based, compounds are s...

Rapid changes in redox potential (Eh) and pH occur in wetland environments. Due to frequent hydrologic fluctuations, wetland soils and sediments can have Eh values ranging from 700 mV (under drainage conditions) to −300 mV (under prolonged flooding conditions). Redox potential is probably the best available simple indicator of the oxidation– reduction status of a system, and it covers the entir...