The character of the electronic transitions in the ultraviolet-visible-near infrared (UV-vis-NIR) spectra of platinum-bis(alkynyl) bridged, bis-triarylamine mixed-valence systems trans-[Pt(C≡CC6H4NAr2)2 (PR3)2](n+) (R = ethyl, Ar = C6H4CH3-4 (1) or C6H4OCH3-4 (2); R = Ph, Ar = C6H4CH3-4 (3) or C6H4OCH3-4 (4), n = 0, 1, 2) has been determined from a combination of spectroscopic measurement and d...

  Abstract : The main objective of this study is estimating the strong motion for the Bam region using the stochastically based seismological models. The two widely used synthetic techniques namely point-source and finite-fault were utilized incorporating the source-path and site parameters into simple function. The decay factor kappa was estimated based on the data obtained from recorded stron...

Five new homoleptic [NiX(4)](2-) compounds have been prepared with the fluorinated ligands OC(6)F(5) (OAr(F)), OC(6)H(3)(CF(3))(2) (OAr'), and OC(4)F(9) (OR(F)) and characterized with X-ray crystallography, magnetic susceptibility, and elemental analysis. Electronic spectral studies show that these ligands engender a ligand-field environment similar to that of fluoride and thus act electronical...

ground vibrations during an earthquake can severely damage structures and equipments housed in them. many factors including earthquake magnitude, distance from the fault or epicenter, duration of strong shaking, soil condition of the site, and the frequency content of the motion define the properties of ground motion and its amplification. a deep understanding of the effects of these factors on...

In this paper we explore the use of the novel relativistic intermediate Hamiltonian Fock-space coupled-cluster method in the calculation of the electronic spectrum for small actinyl ions (NpO2+, NpO2(2+), and PuO2(2+)). It is established that the method, in combination with uncontracted double-zeta quality basis sets, yields excitation energies in good agreement with experimental values, and be...

Recently, concerning failure of structures due to earthquakes, special investigations of near fault ground motions have been noticed. Hence, in this paper, characteristics of near field ground motions have been considered in horizontal and vertical directions. In this consideration, the record averages have been compared with Uniform Building Code and Eurocode8 spectra in two levels. In additio...

The observation of long-lived electronic quantum coherence in a photosynthetic light harvesting system [Engel et al. Nature 2007, 446, 782] has led to much effort being devoted to elucidation of the quantum mechanisms of the photosynthetic excitation energy transfer. In this paper we examine the question of whether the decay of the coherent beating signal is due to quantum mechanical decoherenc...