A novel Schiff base was synthesized by the reaction of piperonal and anthranilic acid, which was further utilized in the synthesis of five novel complexes by reaction with different metal salts ultrasonically. Time for the reaction was greatly reduced through ultrasound irradiations and the yield of reactions was also high as compared to the conventional methods using reflux conditions. The...

Schiff base complexes of transition metals are of particular interest to inorganic chemists because of their structural, spectral and chemical properties, which are often strongly dependant on the nature of the ligand structure. Large number of metal (II) complexes with Schiff-base ligands has been extensively studied for their interesting structural specialties, applications and properties. Th...

the reaction of copper(ii) chloride and zinc(ii) chloride with n-(2-methylphenyl)-3-(1'-salicylaldehydene-2'-imine-ethane)-butanamide(h2l2a) or (mpsb), n-(2-methylphenyl)-3-(1'-(3'-methoxysalicylaldehydene-2'-imine-ethane)-butanamide (h2l2b) or (mpmsb) and n-(2-methylphenyl)-3-(1'-(2'-hydroxyacetylene-2'-imine-ethane)-butanamide (h2l2c) (mphb) leads to th...

New two nano- sized Schiff base complexes [M(L)], where L= 2, 2'-((1E, 1E')-(1, 2 phenylen bis (azanylylidene)) bis (methanylylidene)) bis (4-bromo phenolato) and M=Cu or Zn, (a, b complexes) were synthesized by ultrasonic irradiation. These complexes were characterized by elemental analysis, molar conductivity, FT-IR, fluorescence emission, 1H NMR, field emission scanning electron spectroscopy...

Schiff base denotes a reaction product of a primary amine and a carbonyl compound. Schiff bases possess a wide variety of biological activity specially antibacterial and antifungal properties. Metal complexes of Schiff base have been studied for their biological activities. This review articles provide a summary of medicinal chemistry features of Schiff base and various reports published on bio...

in this paper, we report the synthesis and characterization of a new symmetric macroacyclic schiff base ligand (h2l) and related complexes with different metals. (h2l) was synthesized by the one pot condensation reaction of 2-[2-(2-formyl phenoxy)ethoxy]benzaldehyde and 2-aminobenzenethiol in a 1:2 molar ratio. the acyclic schiff base was characterized by ir, nmr spectroscopy and elemental anal...

New two nano- sized Schiff base complexes [M(L)], where L= 2, 2'-((1E, 1E')-(1, 2 phenylen bis (azanylylidene)) bis (methanylylidene)) bis (4-bromo phenolato) and M=Cu or Zn, (a, b complexes) were synthesized by ultrasonic irradiation. These complexes were characterized by elemental analysis, molar conductivity, FT-IR, fluorescence emission, 1H NMR, field emission scanning electron spectroscopy...

In this paper, we report the synthesis and characterization of a new symmetric macroacyclic Schiff base ligand (H2L) and related complexes with different metals. (H2L) was synthesized by the one pot condensation reaction of 2-[2-(2-formyl phenoxy)ethoxy]benzaldehyde and 2-aminobenzenethiol in a 1:2 molar ratio. The acyclic Schiff base was characterized by IR, NMR spectroscopy and elemental anal...

Five rare earth complexeslanthanum(III),praseodymium(III),neodymium(III), samarium(III) and europium(III) have been synthesized from Schiff base ligand (N,N-bis (2-hydroxy-1-naphthylidene) acetylhydrazone). The complexes were characterized based on elemental analysis, molar conductance, ultraviolet, infrared, mass, thermogravimetric and powder X-ray diffraction studies. Infrared spectra sug...

in this paper, two double helical dinuclear copper(ii) complexes of bis-n,o-bidentate schiff base ligands bis(3-methoxy-n-salicylidene-4,4'-diaminodiphenyl)sulfone (l1) and bis(5-bromo-n-salicylidene-4,4'-diaminodiphenyl)sulfone (l2) were prepared and characterized by elemental analyses (chn), as well as thermal analysis. elemental analyses (chn) suggested that the reaction between ligands and ...