The influence of NaNO2, HNO3 and H2SO4 on the structure and morphology of gamma-alumina was investigated by XRD, BET, SEM and FT-IR spectroscopy. Selected amounts of NaNO2, HNO3 and H2SO4 were added to a solution of aluminum isopropoxide (as a precursor for the boehmite synthesis). The boehmite samples were calcined at 350 and 600 ℃ to form the semi-crystalline high surface area gamma-Al2O3. Th...

We present the VRAI-selectivity program which predicts major product and selectivity not only for transition-state controlled reactions but also processes by reaction dynamics.

the mono-metallic and bi-metallic catalysts have been prepared by impregnating with solutions containing a compound of h2ptcl6,wo3 and 1ml hcl (0.1 mol). it should be noted that the catalysts’ activity and selectivity have been determined under these conditions : 450-5000c ,and 15-25atm by h2. for converting n-heptane , the molar ratio h2/c7h16 is 5 , and lhsv is 1.5ml/h. it has been proved tha...

fine particles silicoaluminophosphate-34 were synthesized by hydrothermal sol-gel method. the effect of crystallization time, as one of the important synthesis factors on particle size and crystallinity, kinetic and equilibrium adsorption, and selectivity of co2 / ch4 has been studied in this work. the adsorption isotherms are obtained at moderate gauge pressures (100-3000 kpa) and temperatures...

the catalyst pt-ta supported on 7-alumina was prepared by impregnation with solution containing compoundsof ii21k1.0. and ta205 the pt concentration was kept constant at 0.2 vet% while the concentration of thetantalum was 0,4 wt%. the activity and selectivity of catalyst were determined under conditions at 450-500 °cand 15-30 atm.. with molar ratio h2/c[h,e5 and wh=1.5ml/h for converted n-hepta...

The catalyst Pt-Ta supported on 7-alumina was prepared by impregnation with solution containing compoundsof II21K1.0. and Ta205 The Pt concentration was kept constant at 0.2 vet% while the concentration of thetantalum was 0,4 wt%. The activity and selectivity of catalyst were determined under conditions at 450-500 °Cand 15-30 atm.. with molar ratio H2/C[H,e5 and WH=1.5mL/h for converted n-hepta...

ch4, c2h6 and c2h4 are the most important outlet gaseous of oxidative couple methane (ocm) reaction and this process is a new technology for conversion of natural gas to ethane and ethylene products. in this study, adsorption of ocm outlet hydrocarbons over 10x zeolite has been examined at equilibrium conditions. temperature and pressure are the most effective operational parameters in the batc...

the oxidative coupling of methane (ocm) performance over na-w-mn/sio2 at elevated pressures has been simulated by adaptive neuro fuzzy inference system (anfis) using reaction data gathered in an isothermal fixed bed microreactor. in the designed neuro fuzzy models, three important parameters such as methane to oxygen ratio, gas hourly space velocity (ghsv), and reaction temperature were conside...

bimetallic pt-v supported by gamma-alumina is used to observe the changes of nheptanewhen passed over this catalyst. the pt concentration was kept constant at0.1wt% while the concentration of the vanadium was 0.5wt%. the activity andselectivity of catalyst have been determined under conditions at 450-500 degreescentigrade and 15-30 attn. the experimental results show that the addition of second...