نتایج جستجو برای: si 2
تعداد نتایج: 2581648 فیلتر نتایج به سال:
در این تحقیق، شبیه سازی آستنیته کردن چدن نشکن با ترکیب 0/23mn - si 2 - 3/5c و 0/82mn - si 2 - 3/5c درصد وزنی و به ترتیب با ساختار فریتی و پرلیتی انجام شد و جهت شبیه سازی پارامترهای مهمی نظیر انتقال حرارت ، جدایش ، دماهای بحرانی آستنیته کردن و نفوذ کربن در نظر گرفته شد.
In a previous communication, we showed that a single Au atom behaves like H in its bonding to Si in a series of Si-Au clusters, SiAu(n) (n = 2-4) (Kiran et al. Angew. Chem., Int. Ed. 2004, 43, 2125). In this article, we show that the H analogy of Au is more general. We find that the chemical bonding and potential energy surfaces of two disilicon Au clusters, Si(2)Au(2) and Si(2)Au(4), are analo...
Hydrogen-terminated, chlorine-terminated, and alkyl-terminated crystalline Si(111) surfaces have been characterized using high-resolution, soft X-ray photoelectron spectroscopy from a synchrotron radiation source. The H-terminated Si(111) surface displayed a Si 2p(3/2) peak at a binding energy 0.15 eV higher than the bulk Si 2p(3/2) peak. The integrated area of this shifted peak corresponded to...
The synthesis and structure of a dimeric aluminium hydroxide complex containing the novel chelating 1,4-disiloxide ligand [CH(2){Me(Me(3)Si)(2)Si}(2)SiO](2)(2-) (2)-2H is reported. [CH(2){Me(Me(3)Si)(2)Si}(2)SiO](2)AlOH (4) was prepared by careful hydrolysis of [CH(2){Me(Me(3)Si)(2)Si}(2)SiO](2)AlMe·THF (3).
Silicon is not an essential element for plant and commonly recognized as "quasi-essential" elements, however its beneficial effect on the plants growth has been well known. In present study the effects of 0, 0.2, 1, 2, 4 and 6 mM of Si on the 5-weeks old maize plant under hydroponic condition were investigated and the data was analyzed by heatmaps. The results showed that the application of Si ...
objective: silicon is an effective element in bone biomineralization; hence si-substituted hydroxyapatite can be a relevant bioceramic as bone materials substitution. materials and methods: stoichiometric hydroxyapatite (ha) and si-substituted hydroxyapatite (si-ha) with different contents of si substitution were synthesized successfully by a hydrothermal method using ca(no3)2, (nh4)3po4 or (n...
The preparation of silylamide Hauser base (R2NMgX; X = halide) and amido-Grignard (R2NMgR) complexes from simple Grignard reagents using [K{N(SiMe2(t)Bu)2}]n, [K{N(SiMe2(t)Bu)(Si(i)Pr3)}]n and [K{N(Si(i)Pr3)2}]n, and their parent silylamines, was explored. Both salt metathesis and protonolysis routes proved ineffective with allylmagnesium chloride as a starting material due to complex Schlenk e...
Compositions of Al2O3+Si, SiO2+Al and Al+Si systems were prepared to study the effect of reaction bonding process on the mullite formation. The composition of each system was adopted according to mullite stoichiometery and sintered in 700-1600°C range. Results showed that the formation of reaction bonded mullite starting from Al2O3+Si mixtures, proceeded in two partially overlapping steps, the ...
[Me(2)Si(Cp(Me(2)))(2)]W(H)Cl is obtained via reaction of WCl(6) with a mixture of [Me(2)Si(Cp(Me(2)))(2)]Li(2) and NaBH(4), from which the dichloride [Me(2)Si(Cp(Me(2)))(2)]WCl(2) is obtained via treatment with CHCl(3). [Me(2)Si(Cp(Me(2)))(2)]WCl(2) provides a means to access other ansa tungstenocene compounds, such as [Me(2)Si(Cp(Me(2)))(2)]WH(2), [Me(2)Si(Cp(Me(2)))(2)]WMe(2), and [Me(2)Si(C...
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