A new synthetic route to mechanochemically produce silicon nanoparticles modified with biocompatible and chromophoric molecular compounds using the Williamson ether synthesis is described. This reaction allows a direct grafting of organic compounds such as phenol, hydroquinone and tetraethylene glycol to the silicon nanoparticle surface in an efficient fashion. Specifically, the formation of (p...

the six elements commonly known as metalloids are boron, silicon, germanium, arsenic, antimony, and tellurium. metalloid containing compounds have been used as antiprotozoal drugs. boron-based drugs, the benzoxaboroles have been exploited as potential treatments for neglected tropical diseases. arsenic has been used as a medicinal agent and arsphenamine was the main drug used to treat syphilis....

Titanium-silicon alloys have been electrochemically extracted from the multi-component titanium compounds in molten calcium chloride electrolyte. Sintered pressed pellets of titanium-bearing compounds served as the cathode, and the electrochemical experiments were systematically carried out at 900 °C, 3.1 V and 1000 °C, 3.8 V using a graphite-based anode and an improved inert-oxygen-ion-conduct...

BACKGROUND Some metallic compounds, especially of zirconium, can cause cell mediated granulomatous inflammation of the skin. Pigment granules containing compounds of aluminium, silicon, and titanium have been observed within macrophages in the wall of the small intestine in health and in Crohn's disease. Zirconium compounds can be ingested in toothpaste. AIM To determine in a pilot study if g...

Silicon (Si) is the most abundant element present in the Earth's crust besides oxygen. However, the exact biological roles of silicon remain unknown. Moreover, the ortho-silicic acid (H4SiO4), as a major form of bioavailable silicon for both humans and animals, has not been given adequate attention so far. Silicon has already been associated with bone mineralization, collagen synthesis, skin, h...

The synthesis, crystal structure, and characterization of a silicon–silicon triply bonded species, disilyne with two bis[bis(trimethylsilyl)methyl]isopropylsilyl substituents, are described. The nature of the sp-hybridized silicon atoms is discussed from the viewpoint of spectroscopic results and theoretical calculations. The reactivity of the disilyne with alkali metals, tBuLi, and π-bonded co...

The reaction of sodium hydro-tris(phenylthioimidazolyl)borate (NaTm) with silicon tetraiodide gives rise to the first crystallographically characterised molecular silicon compounds, [Si(Tm)2] 2X (X = I and I3 ), in which the silicon is found in a regular S6 environment. The [Si(Tm)2] 2+ cation is subjected to analysis using DFT methods to explain why an S6 coordination motif is preferred to an ...