Optical properties of silver Ag(n) nanoclusters are demonstrated to be dependent on their size, structure and charge state. It is found that when being contained in the sodalite cavity of LTA zeolite the tetradecanuclear hexacation silver cluster Ag14(6+) is stable. Its lower-lying states and optical spectrum are theoretically determined using the quantum chemical TD-DFT method. Its ground stat...

this study was carried out to evaluate how various amounts of nanozeolite decrease the effects of aflatoxins (af) on color and oxidative stability of the broiler thigh meat. three hundred and thirty six one-day-old ross 308 male broiler chickens were divided into six groups including a control group, which received diet without af and nanozeolite, and five treatment groups that received diet wi...

(ABSTRACT) Several novel silica structures have been generated using a simulated-annealing strategy with an ab-initio based covalent-bonding potential. First-principles total-energy pseu-dopotential methods have been used to examine several promising novel structures and to compare their structural parameters, cohesive energies and bulk moduli with those of low-quartz, low-cristobalite, silica-...

perlite or pearl stone is a natural glass which has formed by rapid cooling of viscous lava or magma. perlite is mainly composed of silica, aluminum, potassium and sodium. in this experiment, perlite was used as a low-cost source of si and al to synthesis of sodalite zeolite using the alkaline hydrothermal treatment. a statistical taguchi design of experiments was employed to evaluate the effec...

a novel modified ni-zsm-5 nanozeolite was fabricated via an organic template-free hydrothermal route. the average particle size of ni-zsm-5 nanozeolite was calculated to be 85 nm by scanning electronic microscopy. then, carbon paste electrode (cpe) was modified by ni-zsm-5 nanozeolite and ni2+ ions were then incorporated to the nanozeolite matrix. electrochemical behavior of this electrode was ...

Franzinite, ideally [(Na,K)30Ca10][Si30Al30O120](SO4)10•2H2O, a feldspathoid belonging to the cancrinite group, has a tenlayer stacking sequence. Its structure was solved in the space group P321 to an R value of 5.96%. Cell parameters are a 12.916(1), c 26.543(3) Å. The framework, characterized by the stacking sequence ABCABACABC, contains regular alternations of two “cancrinite” and two “sodal...

A novel modified Ni-ZSM-5 nanozeolite was fabricated via an organic template-free hydrothermal route. The average particle size of Ni-ZSM-5 nanozeolite was calculated to be 85 nm by scanning electronic microscopy. Then, Carbon paste electrode (CPE) was modified by Ni-ZSM-5 nanozeolite and Ni2+ ions were then incorporated to the nanozeolite matrix. Electrochemical behavior of this electrode was ...

Introduction: The search for the former existence in the Early Solar System of the now extinct radionuclide Cl (T1⁄2 = 3x10 a) has proven to be difficult [e.g., 1]. This is at least partly due to the volatility of chlorine and the fact that in primitive meteorites Cl occurs in high abundance only in alteration phases such as sodalite (Na8Al6Si6O24Cl2). 36-Cl decays to both Ar by β decay (98.1 %...

In this paper, we present the possibility of using fly ash to produce synthetic zeolites. The synthesis class F fly ash from the Stalowa Wola SA heat and power plant was subjected to 24 h hydrothermal reaction with sodium hydroxide. Depending on the reaction conditions, three types of synthetic zeolites were formed: Na-X (20 g fly ash, 0.5 dm(3) of 3 mol · dm(-3) NaOH, 75 °C), Na-P1 (20 g fly a...

The structural behavior of a chromate aluminate sodalite, Ca8[Al12O24](CrO4)2, at room pressure and on heating from 463 to 982°C was determined by using in situ synchrotron X-ray powder-diffraction data [ = 0.91997(4) Å] and Rietveld refinements. The sample was heated at a rate of about 9.5°C/min., and X-ray traces were collected at intervals of about 17°C. The structure at 463°C is a modulated...