Many metal-organic frameworks are water labile, including the iconic Hong-Kong University of Science and Technology-1 (HKUST-1). Spray-dry encapsulation of HKUST-1 crystals into polystyrene microspheres is reported here to yield composites that are resistant to water but retain most of the excellent gas sorption capacity of HKUST-1. These composites are demonstrated to exhibit superior water ad...

Humic acids and clays are important soil components that influence the sorption and desorption of organic contaminants; however, it is unclear how humic acids influence the sorption of organic contaminants onto clays and their subsequent desorption. Sorption and desorption of 2,4,6-trichlorophenol (2,4,6-TCP) by and from humic acid-modified K(+)- and Ca(2+)-montmorillonite and -illite were comp...

Potent estrogenic hormones are consistently detected in the environment at low concentration, yet these chemicals are strongly sorbed to soil and are labile. The objective of this research was to improve the understanding of the processes of sorption, mobility, and transformation for estrogens in natural soils, and their interaction. Equilibrium and kinetic batch sorption experiments, and a lon...

One of the methods of disposal of sewage sludge, which is based on its fertilizing properties, is its use in nature, e.g. in farming (if all the permissible standards are met). However, the sludge used for soil fertilization might also contain heavy metals which cause soil contamination and are accumulated in plants. The effect of application of organic fertilizers on soil reaction and other pr...

salicylic acid is an important organic acid in plants rhizosphere soil exuded in the phosphorus (p) deficiency condition. to study the sorption behavior of p in the presence of salicylic acid, a batch experiment was conducted with different concentrations of salicylic acid (0, 2, 5 and 10mm) and p (0- 45 mg p/l) in a calcareous soil. the results showed that application salicylic acid decreased ...

In this study the main physical-chemical characteristics of red ferralitic soil to use as substrate in subsurface wetlands was determined. The P-removal was evaluated in a short-term isotherm batch experiment and in a column percolation experiment. The acid characteristic and high content of iron minerals in the red ferralitic soil facilitated the phosphorus removal. Also the sorption isotherms...

A topologically interesting nanoporous In-MOF, (Et(2)NH(2))[In(2,6-NDC)(2).2H(2)O.DEF], was prepared and its crystal structure and gas sorption properties were investigated with experiment and calculation.

Atsushi Kondo,† Hiroshi Noguchi,† Lucia Carlucci,‡ Davide M. Proserpio,‡ Gianfranco Ciani,‡ Hiroshi Kajiro,*,§ Tomonori Ohba,† Hirofumi Kanoh,*,† and Katsumi Kaneko† Graduate School of Science, Chiba UniVersity, Yayoi, Inage, Chiba 263-8522, Japan, Nippon Steel Corporation, Shintomi, Futtsu, Chiba 293-8511, Japan, and Dipartimento di Chimica Strutturale e Stereochimica Inorganica, UniVersità di...

UNLABELLED As acidic monomers of self-etching adhesives are incorporated into dental adhesives at high concentrations, the adhesive becomes more hydrophilic. Water sorption by polymers causes plasticization and lowers mechanical properties. The purpose of this study was to compare the water sorption and modulus of elasticity (E) of five experimental neat resins (EX) of increasing hydrophilicity...

Concentrations of dissolved selenium (Se) as large as 330 pg L-' have been detected in water samples &om bacW aquifers in the southern Powder River Basin (PRB) of northeastern Wyoming. During d a c e coal mining, rock mstwial overiymg the coal is redistributed in relation to its original stratigraphic position; exposure of the prewiously buried material to surface oxidizing conditions decreases...