A sensitive, selective and simple method for the simultaneous determination of carvedilol enantiomers in aqueous solution has been developed using stir bar sorptive extraction (SBSE) followed by high-performance liquid chromatography (HPLC) with ultraviolet (UV) detection. This method is based on the reaction of carvedilol enantiomers with (-)-menthyl chloroformate (MCF) after extraction by the...

Multiple pesticides in water samples were successfully analyzed using an Agilent 5975T LTM GC/MSD equipped with an Agilent J&W DB-5ms Ultra Inert low thermal mass column module, with stir bar sorptive extraction and an Agilent Thermal Separation Probe for sample preparation. The method was simple, rapid, effective, and showed good linearity (R2 >0.9914) and high sensitivity for most of the targ...

A novel sulfamethazine molecularly imprinted polymer (MIP)-coated stir bar for sorptive extraction of eight sulfa drugs from biological samples was prepared. The MIP-coating was about 20 μm thickness with the relative standard deviation (RSD) of 6.7% (n=10). It was characterized by scanning electron microscope, infrared spectrum, thermogravimetric analysis, and solvent-resistant investigation, ...

Tamarind seed, a household waste from the kitchen is used for the sorptive removal of fluoride from synthetic aqueous solution as well as from field water samples. Batch sorptive defluoridation was conducted under variable experimental conditions such as pH, agitation time, initial fluoride concentration, particle size and sorbent dose. Maximum defluoridation was achieved at pH 7.0. Defluoridat...

This article reviews the recent developments in Bio-Analytical sample preparation techniques and gives an update on basic principles, Applications and comparative discussion on the advantages and limitations of each technique. Conventional Solid-Phase Extraction (SPE), Molecularly Imprinted Polymer SPE techniques are have been considered as methods of past. Developments in SPE techniques such a...

A method of sample preparation based on use of rotating disk sorptive extraction (RDSE) has been developed for determination of triclosan (TCS) and methyl-triclosan (MTCS) in water samples. The sorptive and desorptive behavior of the analytes was studied by use of a rotating disk coated with polydimethylsiloxane (PDMS) on one of its surfaces. Chemical and extraction behavior were studied to est...

An analytical study is presented of dispersion in steady and oscillatory open-channel flows under the combined effects due to reversible sorptive phase exchange with the bed and irreversible air–water reaction on the free surface. The free-surface reaction is assumed to be so weak that the asymptotic mean concentration can be developed well before undue substantial loss to the air occurs. The e...

Wood consists mainly of three types of polymers; cellulose, hemi cellulose and lignin. Lignin is formed in nature through enzymatic initiated oxidative coupling of three different kinds of phenyl propane units. These form by various carbon-carbon and carbon-oxygen bonds, an amorphous three-dimensional polymer. As chemical pulp is produced, lignin is degraded and dissolved into pulping liquors. ...

A multi-residue method for determination of fi ve groups of 85 pesticides organochlorine, carbamate, organophosphorous, pyrethroid and others in non-fatty food, e.g. vegetables, fruits and green tea is described. The method is based on stir bar sorptive extraction (SBSE) coupled to thermal desorption (TD) and retention time locked (RTL) GC-MS