Proton exchange membranes (PEMs) play an important role in the fuel cell systems. A good PEM must meet a series of requirements such as high proton conductivity, excellent mechanical strength and stability, chemical and electrochemical stability, low fuel crossover, etc. Nafion is currently the most commercially utilized electrolyte membranes for polymer electrolyte fuel cells, with high chemic...

Abstract Enhancing the proton conductivity of exchange membranes (PEMs) is essential to expand applications membrane fuel cells (PEMFCs). Inspired by conduction mechanism bacteriorhodopsin, cucurbit[ n ]urils (CB[ ], where number glycoluril units, = 6, 7, or 8) are introduced into sulfonated poly(ether ether ketone) (SPEEK) matrix fabricate hybrid PEMs, employing a nature-inspired chemical engi...

Proton transfer in polymer electrolyte membrane is an essential mechanism fuel cell (PEMFC). The development of PEM mostly relies on modification with proton conductive species followed by casting. This brings the random existence to result a limit conductivity. present work proposes alignment species, i.e., donor and acceptor chains, through surface-initiated polymerization so that proceeds ef...

Advanced polymer composite membranes were prepared from a linear sulphonated poly(ether ether ketone) (SPEEK) with bismuth cobalt zinc oxide [BCZO, (Bi2O3)0.07(CoO)0.03(ZnO)0.90] nanopowder as an inorganic additive for the application of H2–O2 fuel cell. Morphological data tend to provide evidences incorporation BCZO into SPEEK polymer. Indeed, membrane loaded 7.5 wt.% was identified uptake max...

sulfonated poly (ether ether ketone) (speek) with a low degree of sulfonation (ds = 40%) was prepared for proton exchange membrane fuel cells (pemfc). poly (ether ether ketone) (peek) was sulfonated in concentrated h2so4 under n2 atmosphere and characterized by the hydrogen nuclear magnetic resonance (h-nmr) technique. after preparation of the speek polymer, the obtained polymer was dissolved i...

Sulfonated poly (ether ether ketone) (SPEEK) with a low degree of sulfonation (DS = 40%) was prepared for proton exchange membrane fuel cells (PEMFC). Poly (ether ether ketone) (PEEK) was sulfonated in concentrated H2SO4 under N2 atmosphere and characterized by the hydrogen nuclear magnetic resonance (H-NMR) technique. After preparation of the SPEEK polymer, the obtained polymer was dissolved i...

Unprecedented water vapor uptake of 320% was demonstrated with SPEEK at an unexpectedly low degree sulfonation 19% due to the high S–S distance.

Proton exchange membranes (PEM), which have been commonly used in fuel cells raised interest for the application harsh environments involving ionizing radiation. Therefore, radiation stability and ability to sustain their functionality under environment are of great interest. Within this study, electron beam irradiation dose range from 50 500kGy was evaluate effects on physico-chemical mechanic...

In this chapter research trends followed by various scientific groups for the development of polymeric membranes have been described and reviewed. Most notably, the developments made at Ballard Advanced Materials (BAM) and some of their results are discussed. In general three different approaches have been followed worldwide by various research groups for the development and conception of alter...

Nowadays, proton exchange membrane fuel cells (PEMFCs) are the most promising green energy conversion devices for portable and stationary applications. Traditionally, these devices were based onperfluoro-sulfonic acid electrolytes membranes, given the commercial name Nafion. Nafion is the mostused electrolyte membrane till now; because of its high electrochemical properties su...