Nanocomposite materials containing Cadmium Telluride (CdTe) nanocrystals and [Fe(H-trz)2(trz)]BF4 nanoparticles were synthesized and investigated for the coupling between their photoluminescent and spin crossover properties. The bright CdTe emission around 550 nm was found to decrease reversibly when switching the ferrous complex from the high spin (HS) to the low spin (LS) state, which was att...

The macrocyclic hexanuclear manganese(III) 18-metallacrown-6, [Mn6(pmshz)6(DMF)4(C2H5OH)2]·4DMF (1), where pmshz3− is N-propionyl-N′-5-methylsalicylhydrazide, has been synthesized by self-assembly and structurally characterized. The ring is formed by the succession of six structural moieties of the type [Mn(III)-N-N] with hydrazide N-N groups bridging the ring Mn ions. The ligand enforces the m...

Photoluminescent (PL) properties related to Te(4+) species in zinc borate glasses are examined. Broad emission was observed by the excitation of the PL excitation peak of Te(4+) present at the optical absorption edge. The emission intensity of Te(4+) in 5TeO(2)-50ZnO-45B(2)O(3) glass was thermally quenched in a temperature region over 100 K, suggesting that concentration quenching preferentiall...

Objective(s): Graphene as two-dimensional (2D) materials have attracted wide attention in different fields such as biomedical imaging. Ultra-small graphene nano-sheets (UGNSs) have been designated as low dimensional graphene sheets with lateral dimensions less than few nanometres (≤ 500 nm) in one, two or few layers. Several studies have proven that the process of acidic exfoliation and oxidati...

This Minireview presents and discusses recent developments in photoactive/photoluminescent N-heterocyclic carbene (NHC) transition metal complexes their viability as catalysts bond-forming photocatalysis. Specifically, we summarise key structural motifs adopted by photoactive NHC highlight some of photophysical properties. Representative examples applications photochemical reactions are also sh...

Nanometer sized semiconductors, or quantum dots (QDs) are sought after for their size-dependent photoluminescent properties. The synthesis of QDs in the past has been by the hot solvent injection approach. An alternative to hot solvent injection is aerosol route formation, which has the potential to be a continuous and large scale QD production method. This study focused on; (a) the aerosol rou...

Mesostructured and mesoporous materials are emerging as a new class of optical materials. However, their synthesis is nontrivial. In this work, periodic mesostructured metal complex-containing silicas of MCM- and SBA-type bearing homogeneously distributed photoluminescent tri(8-quinolinolato)aluminum inside the channel walls (denoted as Alq3@PMO-MCM and Alq3@PMO-SBA, respectively) have been ach...

In recent years, photoluminescent gold nanoclusters have attracted considerable interest in both fundamental biomedical research and practical applications. Due to their ultrasmall size, unique molecule-like optical properties, and facile synthesis gold nanoclusters have been considered very promising photoluminescent agents for biosensing, bioimaging, and targeted therapy. Yet, interaction of ...