نتایج جستجو برای: sublimation
تعداد نتایج: 2151 فیلتر نتایج به سال:
Direct measurements of winter water loss due to sublimation were made in a sub-alpine forest in the Rocky Mountains of Colorado. Above-and below-canopy eddy covariance systems indicated substantial losses of winter-season snow accumulation in the form of snowpack (0Ð41 mm d 1) and intercepted snow (0Ð71 mm d 1) sublimation. The partitioning between these over and under story components of water...
Introduction: Interest in buried glacial ice has gained considerable attention in recent years due to its potential as an archive for long-term climate change and as a consequence of recent suggestions that call for relatively young, near-surface buried ice on Mars. Geochemical analyses of ice stored in stagnant debriscovered glaciers in the western Dry Valleys region of Antarctica (stable upla...
Thermodynamic and kinetic approaches for sublimation inside elastoplastic material under tensile stress are developed for large strains. Various conceptual problems related to irreversible plastic deformation are addressed for a spherical bubble. They include definitions of the thermodynamic driving forces and activation energies, nontraditional concepts of a critical nucleus, path dependence o...
In alpine terrain, snow sublimation represents an important component of the winter moisture budget, representing a proportion of precipitation which does not contribute to melt. To quantify its amount we analyze the spatial pattern of snow sublimation at the ground, from a canopy and from turbulent suspension during wind-induced snow transport for a high alpine area in the Berchtesgaden Nation...
Reliable measurements of the sublimation rate of nonuniform layers of trinitrotoluene (TNT) microcrystals were carried out using a quartz crystal microbalance (QCM). The sample layer was prepared by precipitation of TNT from a well-defined volume of its solution in acetonitrile. The TNT solution was placed on the QCM electrode surface to form the precipitated layer of TNT microcrystals. It is s...
Hans Loewald’s understanding of sublimation differs radically from Freud’s use of this term. Whereas Freud saw sublimation as a change of aim, elevating drive-based desire to a higher level of art, for Loewald, sublimation is a process of linking two experiences of reality. I suggest that Loewald’s sublimation combines ideas from his two teachers—Martin Heidegger and Sigmund Freud. Using Heideg...
A sublimation technique was developed to isolate purines and pyrimidines directly from lambda-deoxyribonucleic acid (lambda-DNA) and Escherichia coli cells. The sublimation of adenine, cytosine, guanine, and thymine from lambda-DNA was tested under reduced pressure (approximately 0.5 Torr) at temperatures of >150 degrees C. With the exception of guanine, approximately 60-75% of each base was su...
In situ heating experiments were performed in a transmission electron microscope (TEM) to monitor the thermal stability of silver nanoparticles. The sublimation kinetics from isothermal experiments on individual nanoparticles was used to assess the actual temperatures of the nanoparticles by considering the localized heating from the electron beam. For isolated nanoparticles, beam heating under...
13 The sublimation enthalpy of cubane, a key reference material for force field and quantum mechanical computations, was measured by combining the vaporization enthalpy at T = 298.15 K to the sum of the fusion enthalpy measured at T = 405 K and a solid–solid phase transition that occurs at T = 394 K. The fusion and solid–solid phase transitions were measured previously. A sublimation enthalpy v...
The mechanism for sublimation of NH(4)N(NO(2))(2) (ADN) has been investigated quantum-mechanically with generalized gradient approximation plane-wave density functional theory calculations; the solid surface is represented by a slab model and the periodic boundary conditions are applied. The calculated lattice constants for the bulk ADN, which were found to consist of NH(4)(+)[ON(O)NNO(2)](-) u...
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