Effects of respirable aerosols of sulfuric acid, ammonium sulfate, sodium sulfite, and ammonium persulfate on lungs of rats are reviewed. The literature regarding interactions between ozone or nitrogen dioxide and acidic aerosols (ammonium sulfate, sulfuric acid) is discussed. An unexpected interaction between nitrogen dioxide and sodium chloride aerosol is also discussed. An attempt is made to...

This study investigates the requirements for modeling of acid sulfite pulping with regard to the recovery of cooking chemicals, especially SO2. Such a model has to predict the temporal change of SO2 distribution on solid, liquid and gaseous phase in the digester throughout the whole pulping process, dependent on the pulping parameters: total SO2, free SO2, liquor-towood ratio, temporal temperat...

Sulfur dioxide (SO2) may act as a cocarcinogen with benzo[a]pyrene (BaP) in the respiratory tract. We have modeled this effect by examining the interactions of 7r,8t-dihydroxy-9t,10t-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene (anti-BPDE) with sulfite, the physiological form of SO2, in a murine respiratory epithelial cell line (C10). We exposed C10 cells to [3H]-anti-BPDE and determined the effects...

Nitrogen dioxide (NO2) absorption in aqueous sulfite solutions has recently gained more attention to reduce NOx emissions. The NO2 removal efficiency is strongly influenced by the competing reactions of and oxidation. present study investigates role oxidation at neutral pH. effects concentration, thiosulfate, pH, inlet oxygen concentration on efficiency, rates were investigated under well-contr...

This thesis presents a new experimental setup for surface analysis studies, incorporating chemical information from infrared reflection absorption spectroscopy (IRAS) and quantitative information from quartz crystal microbalance (QCM). The integrated IRAS/QCM surface analysis system enables in situ studies to be conducted of the metal/atmosphere interaction on a sub-monolayer level. In combinat...

Photosynthetic oxygen evolution by isolated spinach (Spinacia oleracea L.) chloroplasts approached complete inhibition in the presence of a 5 mm concentration of sulfur dioxide. A similar inhibition was observed in the presence of equimolar concentrations of bisulfite ions, suggesting a parallel mode of action. In contrast, an equimolar concentration of sulfite ions was markedly less inhibitory...

Two methylotrophic bacterial strains, TR3 and PSCH4, capable of growth on methanesulfonic acid as the sole carbon source were isolated from the marine environment. Methanesulfonic acid metabolism in these strains was initiated by an inducible NADH-dependent monooxygenase, which cleaved methanesulfonic acid into formaldehyde and sulfite. The presence of hydroxypyruvate reductase and the absence ...

Sulfur dioxide and other so-called sulfiting agents as additives in foods and drugs may cause severe allergic reactions in susceptible individuals, especially asthmatics. The most widely used chemical preservatives, they have become a subject of increasing concern since 1976. The issue was recently brought to national attention by a CBS "60 Minutes" report on sulfite sensitivity aired twice in ...

The occurrence of inflammatory processes and of cancer in the human respiratory tract is intimately associated. One of the major factors in this is probably the recruitment of and stimulated activity of polymorphonuclear leukocytes (PML) in conjunction with the ability of these cells to convert various carcinogens to their ultimate active metabolites. In this study, we demonstrate that nitrite ...