نتایج جستجو برای: supercritical
تعداد نتایج: 10552 فیلتر نتایج به سال:
In this work, the characteristics of wood degradation using supercritical alcohols have been studied. Supercritical ethanol and supercritical methanol were used as solvents. The kinetics of wood degradation were analyzed using the nonisothermal weight loss technique with heating rates of 3.1, 9.8, and 14.5 °C/min for ethanol and 5.2, 11.3, and 16.3 °C/min for methanol. Three different kinetic a...
General principles of supercritical fluid extraction technology to raise efficiency are summarized and concluded in this paper. It generalized the present domestic situation of relative research and developed proposals towards kind of charging and discharging continuous components by a new supercritical fluid extraction .It also introduced structures and working principles of device. Keywords— ...
In our current study, supercritical water impregnation (SCWI) was introduced as a unique catalyst preparation method by employing the high diffusivity property of supercritical water. The method allows nano-particles to place on support surfaces in extremely dispersed conditions. The silica-based nanocatalyst granules for this purpose were prepared by initial impregnation of highly porous silic...
Solute-solute and solute-solvent clustering of N,Ndimethylaminobenzonitrile and ethyl N,N-dimethylaminobenzoate in supercritical fluoroform, supercritical carbon dioxide, and supercritical fluoroform-carbon dioxide mixtures are quantitatively evaluated from the dependence of the relative contributions of the locally excited (LE) state and the twisted intramolecular charge transfer (TICT) emissi...
Drill mud is a fluid which is used in oil extraction industries in order to cool and lubricate the drill bit. Due to containing numerous toxic components, it is considered as a hazardous waste which must be treated before discharging to the environment. Current separation techniques for drill cutting treatment can be categorized into three main categories of physical (dewatering), physiochemica...
The advantage of the application of the supercritical extraction in contrast to the conventional methods to prepare micro and nanoparticles is that the product no longer is exposed to high temperatures for a long time. Furthermore, the supercritical extraction offers the possibility to reduce the content of the residual organic solvent in the final product because of the high solubility of orga...
Supercritical fluid CO 2 is an alternative solvent for extraction of metals. The solubility parameter of supercritical CO 2 varies with density resembling that of liquid hexane at moderate pressures in the supercritical region to those of chlorinated solvents at very high pressures. By changing density of supercritical CO 2 , the solvation environment of a metal chelate system can vary continuo...
The dissolution property of the poorly water-soluble drug, flurbiprofen (FP) was improved by a novel supercritical freeze granulation using supercritical carbon dioxide. Supercritical freeze granulation was defined as a production method of the granulated substances by using the dry ice to generate intentionally for the rapid atomization of the supercritical carbon dioxide to the atmospheric pr...
Supercritical fluids have received much attention for analytical and processing applications. In particular, supercritical carbon dioxide has been used to extract relatively non-polar organics from a variety of environmental matrices, and has also been used for chemical processing. While supercritical carbon dioxide is relatively unreactive and is not an efficient solvent for polar organics, su...
Supercritical fluids are increasingly being used and promoted at a laboratory and pilot scale to produce high value, natural bioactives from biologically based raw materials. Supercritical CO2 is overwhelmingly the solvent of choice for these operations, but is largely limited to the processing of dry raw materials and the extraction of low polarity, low molecular weight compounds. The use of c...
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