Several group 11 metal complexes with chiral thiourea organocatalysts have been prepared and tested as organocatalysts. The promising results on the influence of metal-assisted thiourea organocatalysts in the asymmetric Friedel-Crafts alkylation of indole with nitrostyrene are described. Better results with the metal complexes have been achieved because of the cooperative effects between the ch...

Administration of alpha-naphthylthiourea (ANTU) to rats causes damage to pulmonary endothelial cells and possibly mesothelial lining cells that together may account for the massive pleural effusion characteristic of thiourea toxicity. Using 35S-thiourea as a model compound, the extent of binding of 35S to lung proteins correlated well with the extent of edema, suggesting that the extent of bind...

Linear oligomerization of 3,5-dimethyl benzyl alcohol is induced by a montmorillonite clay (Tonsil Optimum Extra), producing 1,3,5,7-tetramethyl-9,10-dihydro-anthracene, which, by loss of protons results in the product 1,3,5,7-tetramethylanthracene. It was also found that the compounds 4-(3´,5´-dimethylbenzyl)-1,3,5,7-tetramethyl-9,10-dihydroanthracece and 4-(3´,5´-dimethylbenzyl)-1,3,5,7-tetra...

however, the conventional gold recovery process is cyanidation, due to the recent environmental laws; researchers are looking for alternative methods for the recovery of gold. furthermore, the copper anode slime is one of the most important secondary sources of gold (about 1200 ppm). so, the main objective of the current work is gold separation from copper anode slime as a rich secondary source...

A series of 15 heteroarotinoids has been prepared and evaluated for activity against Mycobacterium bovis BCG with the thiourea-containing isoxyl (7) (0.5 microg/mL) as the standard. 2,2,4-Trimethyl-2H-chromen-7-yl 4-(methoxycarbonyl)benzoate (8) displayed the most significant activity (2.0-4.0 microg/mL) in terms of the lowest concentration (microg/mL) (MIC, minimum inhibitory concentration) re...

Propachlor and other chloroacetanilide herbicides are frequently detected contaminants of groundwater and surface water in agricultural regions. The purpose of this work was to develop a new approach to remove propachlor residues from the environment via chemical remediation by the nitrification inhibitor thiourea. The transformation processes of propachlor and thiourea mixed in aqueous solutio...

As a fundamental step towards creating a new class of cellulose engineering materials, the proposed research investigated swelling and dissolution of cellulose in NaOH aqueous solvent systems (NaOH/H2O, NaOH/thiourea/H2O and NaOH/thiourea/urea/H2O). The dependence of swelling and dissolution behavior of cellulose fibers on the quality of the solvent was investigated in detail. For the two cellu...

Thiourea single crystals have been grown from aqueous solution by slow cooling technique. The stability of the saturated solutions of different pH values has been assessed by measuring the metastable zone width (MSZW) by a nucleation method. MSZW has been enhanced by the influence of pH of thiourea solution. The growth rate of the thiourea crystal along the c-direction [001] was found faster fo...

Lithiation of 1,2-dichloroor 1,2,3-trichloroferrocene with lithium tetramethylpiperidinide, followed by transmetallation with ZnCl2 and Pd(II)-catalyzed coupling with 2-bromopyridine, yield the pyridylferrocenes [CpFe{C5H2−nCl2+n(2-C5H4N)}] (2a, b, n = 0 or 1) as brown oils of low stability. Recrystallization of 2b produced a small number of X-ray quality crystals, which could be shown to have ...

A novel study of external Brønsted acid-assisted thiourea catalysts in the asymmetric FriedelCrafts alkylation of indoles with nitroalkenes is reported. The final 3-substituted indoles derivatives are synthesized with better results by cooperative effect between chiral thiourea and a Brønsted acid additive (1a·HA), than those obtained with sole thiourea catalyst 1a. The effect of diverse catal...