concentrations of 42 trace elements, including rare earths, in croatian thermal waters wereinvestigated. originating from different parts of croatia, i.e. different types of aquifers, studied thermal watersprovide insight into the range of concentrations of broad spectrum of elements in croatian thermal waters.covering a wide range of temperature (30 - 92 °c), studied thermal waters are general...

Nearly all chemical processes fractionate 17O and 18O in a mass-dependent way relative to 16O, a major exception being the formation of ozone from diatomic oxygen in the presence of UV radiation or electrical discharge. Investigation of oxygen three-isotope behavior during thermal decomposition of naturally occurring carbonates of calcium and magnesium in vacuo has revealed that, surprisingly, ...

[1] The major element, trace element, and isotopic composition of mid-ocean ridge basalt glasses affected by the Azores hotspot are strongly correlated with H2O content of the glass. Distinguishing the relative importance of source chemistry and potential temperature in ridge-hotspot interaction therefore requires a comprehensive model that accounts for the effect of H2O in the source on meltin...

A series of laboratory studies were conducted to increase understanding of stable carbon (C/C) and hydrogen (D/H) isotope fractionation arising from methanogenesis by moderately thermophilic acetateand hydrogen-consuming methanogens. Studies of the aceticlastic reaction were conducted with two closely related strains of Methanosaeta thermophila. Results demonstrate a carbon isotope fractionatio...

A rational approach to the design of clinical protocols combining fractionated hyperthermia plus X-irradiation or hyperthermia plus chemotherapy requires an understand ing of the biology of fractionated heat alone. Mammalian cells growing in vitro can dramatically increase their tolerance to thermal damage (i.e., reduce the cellular inactivation rate) after prior heat conditioning. Although the...

Thermal denaturation of plant ribosomal RNA followed by gel fractionation shows that although a large percentage of molecules contain breaks in the polynucleotide chain, 25S and 18S RNAs do exist as unique molecular species. Values for the rate constant of hydrolysis under routine denaturing conditions are of the order of 10(-7) to 10(-8) sec(- 1) and these are shown not to be a result of ribon...

Ethylene / 1-butene copolymers at different comonomer levels were synthesized using Ziegler-Natta catalyst to evaluate the applicability of thermal fractionation methods in predicting chemical composition distribution (CCD). The continuous melting endotherms by DSC were converted to continuous CCD, and the average comonomer contents were compared with NMR results. DSC underestimated comonomer c...

In this article, we elaborate the application of thermal decomposition based synthesis of Fe3O4 superparamagnetic nanoparticle (SPMNP) in subcellular fractionation context. Here, we performed surface functionalization of SPMNP with phospholipids and dimercaptosuccinic acid. Surprisingly, we observed surface functionalization dependent SPMNP localization in subcellular compartments such as plasm...

To further unlock kraft lignin's potential in material applications, we show that tight control can be achieved over a key physicochemical lignin parameter, its T g , which largely determines, and serves as proxy for, the properties of lignin-derived thermoset materials.