thermal cracking of a heavy liquid hydrocarbon was performed in a laboratory scale tubular reactor. central composite design (ccd), was used as an experimental design method. the design variables were coil outlet temperature (cot), feed flow and rate steam ratio. maximum yield of ethylene was 30.37 wt% at cot, residence time and steam ratio of 869oc, 0.208 s and 1.22 g/g, respectively. maximum ...

In-bulk recording without cracking in borosilicate glass by high repetition rate (80 MHz) 12 ps pulses at 355 nm wavelength is demonstrated and discussed. The theoretical model of a “hot-line” scan and thermal accumulation qualitatively well describes the experimental results. The analytical expression of a thermally induced stress was obtained. © 2004 American Institute of Physics. [DOI: 10.10...

We report the thermally induced unconventional cracking of graphene to generate zigzag edges. This crystallography-selective cracking was observed for as-grown graphene films immediately following the cooling process subsequent to chemical vapor deposition (CVD) on Cu foil. Results from Raman spectroscopy show that the crack-derived edges have smoother zigzag edges than the chemically formed gr...

The biaxial stress and thermal expansion of multilayer doped-aluminosilicate environmental barrier coatings were measured in-situ during cooling using microfocused high-energy X-rays in transmission. Coating stresses during cooling from 1000oC were measured for as-sprayed and thermally cycled samples. In the as-sprayed state, tensile stresses as high as 75 MPa were measured in the doped-alumino...

The origins of fractures in Martian boulders are unknown. Here, using Mars Exploration Rover 3D data products, we obtain orientation measurements for 1,857 cracks visible in 1,573 rocks along the Spirit traverse and find that Mars rock cracks are oriented in statistically preferred directions similar to those compiled herein for Earth rock cracks found in mid-latitude deserts. We suggest that M...

Short cracks, extending to the interdiffusion zone, have been observed in platinum-modified nickel-aluminide diffusion coatings on single-crystal CMSX-4 superalloys after these have been subject to short (10 min) rapid thermal cycles. The cracks were revealed after removing the thermally grown oxide formed during cycling on the coating surfaces. Cracking was observed for coatings subject to the...

Direct metal SLS processes use a high power laser beam to selectively fuse fully metallic powder to directly produce functional metal components or tooling. As a thermal dynamic process, it inevitably causes thermal stresses, stress-induced deformations and cracking. Understanding these is very important in controlling residual stresses and stress-induced deformations. In this research, the res...

Holmes and Shuler [1] recently found that significant internal heating occurs during the cyclic loading of fibre-reinforced ceramics. In their investigation, conducted with cross-ply carbon fibre/SiC matrix composites (hereafter referred to as Cf/SiC), it was observed that the extent of internal heating was strongly influenced by the peak fatigue stress and loading frequency. For example, durin...

This review covers recent advances and work on the microstructure features, mechanical properties and cracking processes of conducting polymer film/coating- substrate structures under different testing conditions. An attempt is made to characterize and quantify the relationships between mechanical properties and microstructure features. In addition, the film cracking mechanism on the micro scal...

In conventional WLCSP process, after defining the under bump metal (UBM) layer, a solder ball is dropped in the UBM opening. A subsequent thermal reflow cycle melts the solder ball and cools it in a well defined shape on top of the UBM layer. One draw back of this technology is the fracture or cracking of passivation film that may occur during the solder ball reflow process. The cracks in the p...