The present work aimed to evaluate capability of a new molecular structure to stabilize polyethylene against thermal oxidation. Hence, effects of 3,3-bis(4-hydroxy-2-methyl-5-propan-2-ylphenyl)-2-benzofuran-1-one (thymolphthalein) on thermo-oxidative stability of high density polyethylene (HDPE) in both solid and melt states were investigated and compared with those of SONGNOX 1010, a comme...

In this research oxidation kinetic panceuo.s (P.S) by S2O8-2 at the presence of AgNO3 ascatalyst was studied.The method was spectrophotometer following absorption spectrum (P.S) inwave length of 518 nm. After improving the condition such as PH, P.S concentration, K2S2O8concentration, ionic strength, temperature, rate constant, activation energy, constant frequency,order reaction and thermo dyna...

the present work is aimed to find a new and efficient type of antioxidants for polypropylene. hence, effects of 3,3-bis(4-hydroxy-2-methyl-5-propan-2-ylphenyl)-2-benzofuran-1-one, generally known as thymolphthalein, on thermo-oxidative stability of polypropylene in solid and melt states were evaluated and compared with those of songnox 1010, an efficient commercially used antioxidant for the po...

This technical note presents a coupled thermo-hydromechanical model for unsaturated soil, which can be applied in the context of high temperature. A new pore gas or bulk air transfer equation is introduced. Additionally the effect of temperature on the latent heat of vapourisation and specific heat capacities is incorporated. Adsorbed water is also included. The performance of the model is demo...

Microbial redox reactions of inorganic sulfur compounds are one of the important reactions responsible for the recycling of this element to maintain the environmental sulfur balance. These reactions are carried out by phylogenetically diverse set of microorganisms. The sulfur oxidizing gene cluster (sox) of thermo-neutrophilic bacterium Hydrogenobacter thermophilus consists of soxYZAXB. The bac...

Some years ago, we showed that thermo-chemically denatured, partially-unfolded forms of Pyrococcus furiosus triosephosphateisomerase (PfuTIM) display cold-denaturation upon cooling, and heat-renaturation upon reheating, in proportion with the extent of initial partial unfolding achieved. This was the first time that cold-denaturation was demonstrated for a hyperthermophile protein, following un...

A thermo-morphic transition of a silicon nanowire (Si-NW) is investigated in vacuum and air ambients, and notable differences are found under each ambient. In the vacuum ambient, permanent electrical breakdown occurs as a result of the Joule self-heating arising from the applied voltage across both ends of the Si-NW. The resulting current abruptly declines from a maximum value at the breakdown ...

Refinery sludge is one of the major industrial wastes that needs to be handled and treated . Therefore, this study aim to investigate the Kinetics of devolatilization and oxidation of the refinery sludge collected from a typical petroleum refinery plant located in Malaysia . Thermo Gravimetric Analyzer (TGA) was used in this study for modeling of the devolatilization and oxidation processes in ...