The need for polymers for high-end applications, coupled with the desire to mimic nature's macromolecular machinery fuels the development of innovative synthetic strategies every year. The recently acquired macromolecular-synthetic tools increase the precision and enable the synthesis of polymers with high control and low dispersity. However, regardless of the specificity, the polymerization be...

Ye'elimite occurs in nature and calcium sulfoaluminate cements. The thermodynamic properties of synthetic orthorhombic ye'elimite, Ca4Al6O12SO4, were determined experimentally using low-temperature relaxation calorimetry at higher temperatures differential scanning drop calorimetry. heat capacity, Cp, 480 J/mol/K standard entropy, S°, 487 298 K measured. These values compare well with those cal...

This paper presents a new approach to the observation and the control of the behavior of multiple autonomous robots. It is the microscopic observation expressed by dynamic equations that has been commonly employed to observe the multi-robot behavior. However, the approach has the difficulties in estimating the behavior and the mutual interactions of robots. Furthermore, it is hard to realize th...

Recent years have seen a tremendous progress in the microscopic theoretical treatment of surfaces and processes on surfaces. While some decades ago a phenomenological thermodynamic approach was dominant, a variety of surface properties can now be described from first principles, i.e. without invoking any empirical parameters. Consequently, the field of theoretical surface science is no longer l...

a numerical framework has been proposed to model the interacting effects of mixture non-ideality and mass transfer on hydrodynamics of a multiphase system using cfd methods.mass transfer during condensation and vaporization is modeled by chemical potential at the liquid-vapor interface. species mass transfers are related to the diffusion at the interface which in turn is related to the concentr...

Predicting how cooperative behavior arises in the thermodynamic limit is one of the outstanding problems in evolutionary game theory. For two player games, cooperation is seldom the Nash equilibrium. However, in the thermodynamic limit cooperation is the natural recourse regardless of whether we are dealing with humans or animals. In this work we use the analogy with the Ising model to predict ...

A Bayesian inference methodology is developed for calibrating complex equations of state used in numerical fluid flow solvers. Precisely, the input parameters of three equations of state commonly used for modeling the thermodynamic behavior of so-called dense gas flows, – i.e. flows of gases characterized by high molecular weights and complex molecules, working in thermodynamic conditions close...